Chem 132 Chapter 6&7

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80 Terms

1

In a __________ reaction, two or more elements or compounds form 1 product.

single replacement

dehydration

decomposition

double replacement

combination

combination

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2

A chemical equation is balanced when

the number of atoms of each element is the same in reactants and products.

the total number of molecules is the same in reactants and products.

the total number of ions is the same in reactants and products.

the sum of the coefficients of the reactants is equal to the sum of the coefficients of the products.

the charge on each atom is the same in reactants and products.

 

the number of atoms of each element is the same in reactants and products.

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3

In any balanced chemical equation, the number of each type of atom on both sides of the equation is 

decreased by one.

doubled.

the same.

dependent on the temperature.

increased by one.

 the same.

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4

In the following reaction, when the equation is correctly balanced, what is the correct coefficient for aluminum chloride?

Al(s) + Cl2(g) → AlCl3(s)

1

2

3

4

5

2

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5

The reaction of carbon with oxygen to produce carbon monoxide is an example of which class of reaction?

 2C(s) + O2(g) → 2CO(g)

endothermic

combination

catalytic

double replacement

single replacement

 

combination

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6

The following reaction takes place when an electric current is passed through water. It is an example of a __________ reaction.

2H2O → 2H2 + O2

decomposition

combination

single replacement

dehydration

double replacement

decomposition

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7

What is the classification for this reaction?

 SO3 (g) + H2O (l) → H2SO4(l)

oxidation reduction

combination

replacement

double replacement

decomposition

combination

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8

What is the classification for this unbalanced reaction?

Fe + HCl → FeCl3 + H2

decomposition

double replacement

combination

dehydration

single replacement

single replacement

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9

Which of the following describes an oxidation reaction?

loss of electrons or gain of hydrogen

gain of electrons or gain of oxygen

loss of electrons or gain of oxygen

loss of electrons or loss of oxygen

gain of electrons or loss of H

 

loss of electrons or gain of oxygen

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10

Which of the following is an oxidation-reduction reaction?

CaCl 2 + Na 2SO 4 → CaSO 4 + 2NaCl

AgNO 3 + NaCl → AgCl + NaNO 3

N 2 + O 2 → 2NO

Al 2(SO 4) 3 + 6KOH → 2Al(OH) 3 + 3K 2SO 4

KOH + HNO 3 → H 2O + KNO 3

N 2 + O 2 → 2NO

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11

What type of reaction is: CH4 + 2O2 → CO2 + 2H2O + 218 kcal?

a decomposition reaction

a single replacement reaction

a combination reaction

an exothermic reaction

an endothermic reaction

an exothermic reaction

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12

In an oxidation-reduction reaction, the substance reduced always

takes on oxygen atoms.

shows a gain of electrons.

gives up hydrogen atoms.

shows a loss of electrons.

becomes a charged species.

 shows a gain of electrons.

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13

In an oxidation-reduction reaction, the substance oxidized always

shows a loss of electrons.

becomes a charged species.

takes on oxygen atoms.

gives up hydrogen atoms.

shows a gain of electrons.

shows a loss of electrons.

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14

What is oxidized and what is reduced in the following reaction?

2Al(s) + 3Br2(g) → 2AlBr3(s)

AlBr3 is reduced and Br2 is oxidized.

Al is reduced and Br2 is oxidized.

AlBr3 is oxidized and Al is reduced.

AlBr3 is reduced and Al is oxidized.

Al is oxidized and Br2 is reduced.

Al is oxidized and Br2 is reduced

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15

In this reaction, what is the substance oxidized?

Zn(s) + 2 HCl(aq) → ZnCl2(aq) + H2(g)

zinc chloride

hydrogen

oxygen

zinc

chlorine

zinc

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16

Determine the oxidation state of P in PO33-.

+6

0

+2

+3

-3

+3

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17

Determine the oxidation state of S in MgSO 4.

+6

+4

+2

-4

-2

+6

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18

Determine the oxidation state of Sn in Sn(SO4)2.

+6

0

+4

-2

+2

+4

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19

Determine the oxidizing agent in the following reaction.

Ni(s) + 2 AgClO 4(aq) → Ni(ClO 4) 2(aq) + 2 Ag(s)

Ag

Ni

O

Cl

This is not an oxidation-reduction reaction.

Ag

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20

What element is undergoing oxidation (if any) in the following reaction?

Zn(s) + 2 AgNO3(aq) → Zn(NO3)2(aq) + 2 Ag(s)

N

O

Zn

Ag

This is not an oxidation-reduction reaction.

Zn

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21

What element is undergoing reduction (if any) in the following reaction?

Zn(s) + 2 AgNO3(aq) → Zn(NO3)2(aq) + 2 Ag(s)

N

O

Ag

Zn

This is not an oxidation-reduction reaction.

Ag

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22

What element is undergoing oxidation (if any) in the following reaction?

CH 4(g) + 2 O 2(g) → CO 2(g) + 2 H 2O(g)

H

O

C

both C and H

None of the elements is undergoing oxidation.

C

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23

Identify the oxidation state of Mg in MgCl2(aq).

Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)

+2

+1

0

-2

-1

+2

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24

Identify the oxidation state of Mg in Mg(s).

Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)

0

-1

+2

-2

+1

0

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25

Identify the oxidation state of H in HCl(aq).

Mg(s) + 2HCl(aq) → MgCl 2(aq) + H 2(g)

-2

+2

+1

0

-1

+1

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26

Which of the following is an oxidation-reduction reaction?

NaI(aq) + AgNO3(aq) → AgI(s) + NaNO3(aq)

Mg(s) + 2 HCl(aq) → MgCl2(aq) + H2(g)

HCl(aq) + LiOH(aq) → LiCl(aq) + H2O(l)

Pb(C2H3O2)2(aq) + 2 NaCl(aq) → PbCl2(s) + 2 NaC2H3O2(aq)

All of the above are oxidation-reduction reactions.

 

Mg(s) + 2 HCl(aq) → MgCl2(aq) + H2(g)

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27

34.6 atoms of lithium weigh how many amu's?

240.1586

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28

Avogadro's number is the number of

moles in 6.02 × 1023 amu of an element.

amu in 1 mole of a substance.

moles in 6.02 × 1023 grams of an element.

particles in 1 mole of a substance.

grams in 1 mole of a substance.

particles in 1 mole of a substance.

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29

Calculate the molar mass of magnesium chloride, MgCl2.

24.3 g

95.2 g

59.8 g

70.0 g

125.9 g

95.2 g

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30

The molar mass of calcium hydroxide, Ca(OH) 2, is

74.1 g.

114.2 g.

38.0 g.

58.1 g.

57.1 g.

74.1 g.

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31

Calculate the molar mass of potassium chloride, KCl.

6.74 g

19.0 g

54.5 g

74.6 g

67.4 g

74.6 g

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32

The molar mass of C3H8O2 is

76.0 g.

69.0 g.

60.0 g.

52.0 g.

29.0 g.

76.0 g.

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33

One mole of neon atoms has a mass of

6.02 × 1023 grams.

10.0 g.

14.0 g.

30.2 g.

20.2 g.

20.2 g.

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34

Given the following equation, what is the correct form of the conversion factor needed to convert the number of moles of O2 to the number of moles of Fe2O3 produced?

 4Fe(s) + 3O2 (g) → 2Fe2O3(s)

 

 

 

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35

In the reaction of nitrogen gas, N2, with hydrogen gas, H2, to form ammonia gas, NH3 , how many moles of hydrogen are needed to react with two moles of nitrogen?

6 moles

2 moles

10 moles

4 moles

8 moles

6 moles

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36

In an endothermic reaction,

the products have the same energy that the reactants.

energy is absorbed by the system.

the temperature of the system increases.

the products have less energy that the reactants.

heat flows out of the system.

energy is absorbed by the system.

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37

A reaction that releases energy as it occurs is classified as a(n) __________.

endothermic reaction

catalyzed reaction

oxidation-reduction reaction

decomposition reaction

exothermic reaction

exothermic reaction

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38

Any reaction that absorbs 150 kcal of energy can be classified as __________.

oxidation

activated

reduction

exothermic

endothermic

endothermic

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39

What type of reaction is: CH4 + 2O2 → CO2 + 2H2O + 218 kcal?

a decomposition reaction

a single replacement reaction

a combination reaction

an exothermic reaction

an endothermic reaction

an exothermic reaction

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40

If the reaction shown below is exothermic, the energy level of the reactants is __________.

H2 + O2 → 2H2O

possibly lower, possibly higher than that of the products

lower than that of the products

higher than that of the products

the same as that of the products

higher than the activation energy of the reaction

higher than that of the products

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41

The __________ is the energy difference between reactants and products in a chemical reaction.

product energy

heat of reaction

activation energy

transition energy

overall energy

heat of reaction

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42

The __________ is the minimum energy needed for a chemical reaction to begin.

energy of products

heat of reaction

reaction energy

activation energy

energy of reactants

activation energy

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43

According to the kinetic theory of gases, particles of a gas

move slowly.

are very large.

decrease kinetic energy as temperature increases.

are very far apart.

lose their valence electrons.

are very far apart.

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44

In the kinetic molecular theory of gas behavior, particles of a gas tend to move __________ and collisions between them are __________.

slowly; rare

rapidly; elastic

rapidly; rare

slowly; elastic

slowly; unusual

rapidly; elastic

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45

According to the kinetic theory of gases, a gas can be compressed much more than a liquid or solid because

gas particles move rapidly.

gas particles do not attract or repel one another.

the particles of a gas are very far apart.

a gas is composed of very small particles.

gas particles move faster when the temperature increases.

the particles of a gas are very far apart.

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46

In the kinetic molecular theory of gas behavior, the assumption is made that gas molecules

are attracted to each other by strong forces.

move with a kinetic energy equal to their centigrade temperature.

move rapidly in random directions.

occasionally come to rest.

are close together in their container.

move rapidly in random directions.

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47

Which of the following is NOT part of the kinetic theory of gases?

A gas is composed of very small particles.

Gas particles do not attract or repel one another.

Gas particles move rapidly.

There is very little empty space in a gas.

Gas particles move faster when the temperature increases.

There is very little empty space in a gas.

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48

In a gas, the distance between the particles is

close relative to the size of the molecules.

very large relative to the size of the molecules.

small relative to the size of the molecules.

fixed relative to the size of the molecules.

very close relative to the size of the molecules.

very large relative to the size of the molecules.

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49

The force of gas particles against the walls of a container is called

quantity of gas.

pressure.

volume.

temperature.

density.

pressure.

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50

Which measurement describes the pressure of a gas?

0.45 moles

1.2 g/L

2.5 L

725 mmHg

315 K

725 mmHg

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51

The unit of 1 atmosphere used to describe the pressure of a gas is equal to

760 mmHg.

200 mmHg.

600 mmHg.

100 mmHg.

1 mmHg .

760 mmHg.

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52

The atmospheric pressure is 715 mm Hg. What is the pressure in inches of Hg?

23.9 in Hg

48.6 in Hg

30.0 in Hg

0.940 in Hg

28.1 in Hg

28.1 in Hg

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53

As you rise higher in Earth's atmosphere, the atmospheric pressure

decreases.

remains the same.

increases.

decreases.

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54

According to Boyle's Law, the pressure of a gas increases as the volume decreases because

the gas particles get bigger.

the gas particles strike the walls of the container with more force.

the temperature of the gas increases.

the gas particles strike the walls of the container more often.

the kinetic energy of the gas particles increases.

the gas particles strike the walls of the container more often.

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55

The volume of a gas is inversely proportional to the pressure of a gas is known as

Ideal Gas Law

Charles's Law

Dalton's Law

Boyle's Law

Avogadro's Law

Boyle's Law

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56

A balloon is filled with helium gas. For the question(s) that follow, select the letter of the balloon diagram that corresponds to the given change in conditions.
 

The balloon is put into a chamber whose pressure is less than the atmospheric pressure and at atmospheric temperature.

A

B

C

A and B 

B and C

C

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57

Which of the following correctly describes the process of inspiration (air entering the lungs)?

The lungs expand, causing their internal pressure to increase.

The lungs contract, causing their internal pressure to decrease.

There is no change in the internal pressure in the lungs.

The lungs contract, causing their internal pressure to increase.

The lungs expand, causing their internal pressure to decrease.

The lungs expand, causing their internal pressure to decrease.

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58

What unit of temperature is used in gas law calculations?

degrees Fahrenheit

either degrees Celsius or degrees Fahrenheit

Kelvin

degrees Celsius

either degrees Celsius or Kelvin

Kelvin

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59

The volume of a gas is proportional to the temperature of a gas is known as

Boyle's Law

Dalton's Law

Avogadro's Law

Ideal Gas Law

Charles's Law

Charles's Law

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60

Complete the following statement: In Charles's Law, the volume of a gas __________ when the __________ decreases.

increases; quantity of gas

increases; pressure

decreases; pressure

decreases; temperature

increases; temperature

decreases; temperature

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61

A balloon is filled with helium gas. For the question(s) that follow, select the letter of the balloon diagram that corresponds to the given change in conditions.
 

The temperature is changed from 50 °C to -150 °C at constant pressure.

A

B

C

A and B

B and C

A

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62

In Gay-Lussac's Law, the pressure of a gas increases due to an increase in temperature because

the molecules strike the walls of the container less often.

there is an increase in the number of gas particles.

there is a decrease in the volume of the container.

the molecules strike the walls of the container more often.

the molecules get bigger.

the molecules strike the walls of the container more often.

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63

Vapor pressure can be described as

the temperature at which bubbles of vapor appear in a liquid.

the pressure within the lungs during inhalation.

the temperature at which the vapor pressure of a liquid equals atmospheric pressure.

the pressure exerted by a gas above the surface of its liquid.

the pressure exerted on the Earth by the particles in the air.

the pressure exerted by a gas above the surface of its liquid.

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64

The boiling point of water at sea level is 100 °C. At higher altitudes, the boiling point of water will be

lower, because the atmospheric pressure is lower.

higher, because there are fewer water molecules in the air.

lower, because temperatures are lower.

the same, because water always boils at 100 °C.

higher, because the altitude is greater.

lower, because the atmospheric pressure is lower.

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65

An autoclave is used to sterilize surgical equipment because

it allows water to boil at 100 °C at pressures less than 1 atm.

it allows water to boil at 100 °C at pressures greater than 1 atm.

it allows water to boil at temperatures above 100 °C.

it allows water to boil at temperatures less than 100 °C.

it provides very high temperatures and very low pressures.

it allows water to boil at temperatures above 100 °C.

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66

When the combined gas law is rearranged to solve for V2, the following is the

P2T2/P1V1T1

P1V1T2/P2T1

P1V1/T1 - P2/T2

P1V1T1/P2T2

T2T1V1/P2P1

P1V1T2/P2T1

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67

The volume of a gas is proportional to number of moles of a gas is known as

Avogadro's Law

Boyle's Law

Charles's Law

Dalton's Law

Ideal Gas Law

Avogadro's Law

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68

According to Avogadro's law,

the volume of a gas depends only on the number of moles in the sample.

the volume of a gas is directly related to the number of moles at constant temperature and pressure.

the volume of a gas is inversely related to the number of moles at constant temperature and pressure.

the volume of a gas is inversely related to the number of moles at standard temperature and pressure.

the volume of a gas depends only on the temperature and pressure.

the volume of a gas is directly related to the number of moles at constant temperature and pressure.

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69

At STP, temperature and pressure have the values of

0 K and 1 atm.

0 K and 760 mmHg.

273 K and 760 mmHg.

760 K and 273 atm.

273 K and 1 mmHg.

273 K and 760 mmHg.

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70

Give the temperature and pressure at STP.

0°C and 1 mm Hg

0K and 1.00 atm

25°C and 30.00 in Hg

0°C and 1.00 atm

300K and 1 torr Hg

0°C and 1.00 atm

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71

1 mole of a gas occupies 22.4 L at

0 °C and 760 mmHg.

0 K and 1 atm.

100 °C and 10 atm.

100 °C and 1 atm.

0 °C and 0.50 atm.

0 °C and 760 mmHg.

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72

What volume will 4.91 x 1022 atoms of Ne occupy at STP?

2.00 L

3.11 L

1.10 L

1.83 L

2.24 L

1.83 L

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73

Which of the following samples will have the greatest volume at STP?

22 g CO

22 g O 2

22 g He

22 g Cl 2

All of these samples would have the same volume at STP.

22 g He

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74

Determine the theoretical yield and the percent yield if 21.8 g of K 2CO 3 is produced from reacting 27.9 g KO 2 with 29.0 L of CO 2 (at STP). The molar mass of KO 2 = 71.10 g/mol and K 2CO 3 = 138.21 g/mol.

4 KO 2(s) + 2 CO 2(g) → 2 K 2CO 3(s) + 3 O 2(g)

179 g, 12.2 % yield

91.7 g, 23.8 % yield

61.0 g, 35.7 % yield

206 g, 10.6 % yield

27.1 g, 80.4 % yield

27.1 g, 80.4 % yield

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75

The mathematical expression of the ideal gas law is

 PV  =  nRT

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76

The total pressure in a mixture of gases is equal to the partial pressure(s) of

the gas with the smallest number of moles.

all the gases added together.

the gas with the greatest number of moles.

the gas with the highest molecular weight.

the gas that occupies the largest volume.

all the gases added together.

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77

Which of the following samples will have the lowest pressure if they are all at the same temperature and in identical containers (same volume)?

15 g Ne

15 g Kr

15 g CO 2

15 g F 2

All of these samples will have the same pressure.

15 g Kr

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78

A mixture of 1.0 mol He and 1.0 mol Ne are at STP in a rigid container. Which of the following statements is TRUE?

The mixture has a volume of 22.4 L

Both gases have the same average kinetic energy.

Both gases contribute equally to the density of the mixture under these conditions.

Both gases have the same molecular speed.

All of the above are TRUE.

Both gases have the same average kinetic energy.

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79

The pressure exerted by a gas on the walls of its container is directly proportional to

the mass of the individual gas molecules.

the centigrade temperature of the gas.

the Fahrenheit temperature of the gas.

the number of moles of gas in the sample.

the volume of the container.

the number of moles of gas in the sample.

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80

As the reaction of carbon with oxygen to produce carbon monoxide proceeds in a sealed container at a constant temperature of 600 K, the pressure in the container will __________.

2C(s) + O2(g) → 2CO(g)

increase

decrease

depend on whether a catalyst is present

remain constant

increase

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