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driving force for recovery?
reducing the overall energy of the system by removing stress filled grains and removing dislocations
Graph comparing final grain size vs cold work strain?
decrease in grain size as a function of cold work, as more cold work = more nucleation sites. Also include a gap at the beginning representing the minimum cold work needed
why do grains grow in grain growth
They grow to reduce the overall surface energy of the system by consuming strain filled grains and reducing grain boundaries
what is the difference in bonding between a brittle and plastic polymer
Brittle polymers include more covalent bonds in crosslinkage which causes their brittle behaviors as these dont allow for much flexibility.
Explain the glass transition temperature
the glass transition temperature is the point at which a polymer move from “rubbery to glassy
as the increase in temperature helps increase polymer flexibility as the atoms are more active
What is the driving force for recovery
reducing the overall energy of the system by reducing dislocation density as dislocations reorganize themselves to avoid stress fields
why is there a ductile-brittle transition for BCC but not FCC
FCC metals are abundunt with slip planes where as BCC have limited slip planes so they must be heated up to recieve enough thermal energy for slip to activate
why is there a change in tensile strength during recrystalization
During recrystalization there is an extreme reduction in dislocation density and grain boundaries both of which contribute to a decrease in UTS
What is the driving force for grain growth
reducing overall energy of the system via reducing surface energy and grain boundaries
What will increase the Glass temperature of polymers
anything that increases the stiffness of a polymer such as increasing molecular weight, adding more crosslinks or more double bonds in the backbone as well as more polar side groups
what is vulcanization
vulcanization is the process of adding crosslinks to a polymer which increases the UTS by incorporating stronger covalent bonds as well as creating a more ordered chain increasing crystallinity and E
what are atactic and isotactic polymers and which are more likely
atactic polymers have a random attachment of monomers where as in isotactic they are more ordered and patterned allowing for better mechanical properties and also being more common to crystalize because of this orderdness
under what stress and temperatures does creep occur in
high temps, low stress
why is a lathe formed component so much worse than a polished component under fatique
surface roughness leads to an increase in stress concentrations which will amplify applied stresses proving detrimental under fatigue
what does the force curve look like
basically the opposite version of energy well
would a deep or shallow energy well have a higher elastic modulus
a deep energy well means stronger bonds and thus a stronger response to deformation so it would have a higher elastic modulus
What are 3 needs for elastomers
amorphous structure, free to rotate, above Tg, moderate degree of crosslinking
Describe the UYP, LYP, region W and the top of the stress strain diagram for steel
upper yield point is when the bonds of solute are broken allowing dislocation motion
lower yield point is once solute has had time to redistrubute leading to an increase in stress
Region W is the age hardening of the material as dislocation density increases and dislocation movement becomes harder
The uts is the ultimate tensile strength where necking occurs
What does pre-deformation by drawing in polymers do and what is it
PDD is the stretching of a polymer prior to use, like warming up a muscle it creates a more uniform structure thus increasing E, UTS and decreasign ductility
state how plastic deformation occurs for a plastic polymer and how they deform above and below TG
molecules start straightening out in he non-cystaline regions before elastic deformation begins, next plastic shearing begins as the crystaline blocks break into segments and then amorphous chains.