Organic reactions, reagents and conditions

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10 Terms

1
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Alkane to halogenoalkane (+ mechanism name)

Cl2 or Br2; UV light (free radical substitution)

2
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Alkene to halogenoalkane (+ mechanism name)

HX (gas); rtp (electrophilic addition)

3
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halogenoalkane to alkene (+ mechanism name)

NaOH in ethanol; heat (elimination)

4
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alkene to dihalogenoalkane (+ mechanism name)

Br2 or Cl2; rtp (electrophilic addition)

5
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alcohol to halogenoalkane (+ mechanism name)

  • HX (gas) at rtp

  • KCl and conc. H2SO4 or H3PO4

  • PCl3, heat

  • PCl5 at rtp

  • All nucleophilic substitution EXCEPT

  • SOCl2 at rtp

6
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halogenoalkane to alcohol (+ mechanism name)

NaOH (aq); heat OR AgNO3 (aq) in ethanol; warm (nucleophilic substitution)

7
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Halogenoalkane to amine (+ mechanism name)

NH3 in ethanol; heated under pressure in a sealed tube (nucleophilic substitution)

8
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halogenoalkane to nitrile (+ mechanism name)

KCN in ethanol; heat (nucleophilic substitution)

9
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Alkene to polyalkene (+ mechanism name)

heat and high pressure

10
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alkene to diol (+ mechanism name)

cold, dilute KMnO4 (oxidation)