Reactions of Carbonyls

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6 Terms

1
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NaBH4 (for aldehyde/ketone), LiAlH4 (stronger)

Reduces C=O to OH

forms OH

2
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wittig reagent

Ph3P=Ch2

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3
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Wittig Reagent (Ph3P=CR2)

Converts C=O to C=C

C=C formed

4
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HCN (base catalyzed)

cyanohyrdin formation

adds -CN to carbonyl carbon

5
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1° or 2° amine, acid catalyzed

Nucleophilic addition to C=O, forms C=N or enamine

Imine or enamine

primary amine forms imine

secondary amine forms enamine

6
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imine vs enamine

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