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Addition of H and OH(Mark)- Oxymercuration-Demercuration
intermediates:
Step 1: Hg(OAc)2, H2O, THF(solvent)
Step 2: NaBH4
Addition of H and OR- Alkoxymercuration-Demercuration
Intermediates:
Step 1: Hg(OAc)2, HOR, THF(solvent)
Step 2: NaBH4
Anti-Mark Addition of H and OH
Intermediates:
Step 1: BH3, THR(solvent)
Step 2: H2O2, NaOH, water(solvent)
Anti-Mark Addition of H and Br
Intermediates:
Step 1: HBr, peroxides(ROOR), heat or light
Mark Addition of H and X(X=Cl, Br, or I)
intermediates:
Step 1: HX, cold, dark, no peroxides