write the diagram for carboxylic acid & its derivatives with reagents
carboxylic acid to acyl chloride
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write the diagram for carboxylic acid & its derivatives with reagents
carboxylic acid to acyl chloride
carboxylic acid to anhydride
carboxylic acid to ester
carboxylic acid derivative to amide
carboxylic acid derivative + NH3 = amide
acid chloride
ester
anhydride
amide to nitrile
breakdown of carboxylic acid derivatives
H2O, pyridine
EtOH, pyridine
MeNH2, pyridine
XS LAH, H2O
XS MeMgBr, H2O
Al(OtBu)3H, H2O
Et2CuLi, H2O
H2O, pyridine = carboxylic acid
EtOH, pyridine = ether
MeNH2, pyridine = amide
XS LAH, H2O = primary alcohol
XS MeMgBr, H2O = tertiary alcohol
Al(OtBu)3H, H2O = aldehyde
Et2CuLi, H2O = ketone
breakdown of nitriles
nitrile + H3O+ + H2O = carboxylic acid
nitrile + EtMgBr + H3O+ = ketone