Unit 7: Pollution

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Air Pollution is a global system:

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Air Pollution is a global system:

Introduction of chemicals, particulate matter, or microorganisms into the atmosphere at concentrations high enough to harm plants, animals, and materials such as buildings or into other ecosystems.

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Six outdoor criteria pollutants

-nitrogen oxides

-ozone (ground-level/tropospheric)

-sulfure dioxide

-carbon monoxide

-lead (other toxic metals)

-particulate matter

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Clean air act (1970)

identified 6 pollutants that threaten humans and the environment.

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Nitrogen Oxides

-motor vehicle and fossil fuel combustion

-natural: forest fires, lightning, soil microbes

-Respiratory irritant, acid rain, smog

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Ground-Level Ozone

-Secondary pollutants formed by sunlight and water reacting with VOCs, NOx, and O2

-Respiratory irritant, damages plants

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Sulfure Dioxide

-From combustion of coal and oil (naturally from volcanoes and forest fires)

-Respiratory irritant; affects plant issues

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Carbon monoxide

-Formed during incomplete combustion of most matter

-Vehicle exhaust, other combustion

-Especially dangerous indoors with poor ventilation; manure, charcoal, kerosene

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Lead

-From gasoline (phased out by 1996), paint in older buildings, pipes (flint)

-toxic to the CNS of living organisms

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Particulate Matter

-combustion of fossil fuels and biomass

-diesel much worse than gasoline

-road dust, rock-crushing, volcanoes, fires, and dust storms

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Other Major Pollutants

-hydrocarbons from building supplies and household products

-ex: benzene, toluene, formaldehyde

-coal and oil combustion, concentrations have increased in fish

-mercury

-carbon dioxide

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Primary pollutant

Come directly from source like smokestack or exhaust pipe

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Secondary pollutant

-have undergone transformation in the presence of sunlight, water, oxygen, or other compounds

-occurs more in daytime and in wet conditions

-Ozone, SO3, H2SO4, H2O2, HNO3, PANs

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Noise pollution

Sound at levels high enough to cause physiological stress and hearing loss

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Noise pollution sources

Domestic and industrial buildings, construction, teleportation

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Harmful effects of noise pollution

cognitive, physical, and behavioral

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Indoor Air pollution

Ex: natural; radon, mold, dust

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Radon

naturally occurring radioactive gas, moves up through soil and enters homes via the basement or cracks.

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Anthropogenic

-Insulation

-lead from paint

-VOCs from building materials, furniture, upholstry, and carpeting

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Combustion

-Carbon monoxide

-NOx

-SO2

-Particulate Matter

-Tobacco Matter

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Developing countries

-Indoor burning of wood, charcoal, dung, crop residues, coal

-Poor suffer the greatest risk

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Developed Countries

-Indoor air pollution is a bigger problem than outdoor pollution

-11 of the common air pollutants are higher inside than outside

-Greater in vehicles than outside

-Health risks magnified people spend 90% of their time indoors or in cars

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Main categories of photochemical smog

-Industrial smog

-Sulfurous smog

-London fog

-Winter smog

-Pea soup smog

-Caused by SO2 and particulates reacting with water vapor

-Biggest cause is coal

-Cool, humid conditions

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Photochemical smog

-brown smog

-yellow smog

-Los Angeles smog

-Summer smog

-Caused by VOCs and NOx reacting with water vapor

-Biggest cause is cars (NOx) - Dry, warm conditions

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VOCs

-Organic chemicals (contain the element of carbon) that have a high vapor pressure (evaporate quickly) at room temperature

-Very diverse group

-May be natural (plants) or anthropogenic (solvents, paint, dry cleaning, gasoline)

-Almost all scents you smell are some sort of VOC

-Range from harmless to toxic

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Inversion

-Layer of warm air traps cool air beneath it

-Pollutants get trapped

-Especially in valleys

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Catalytic converters (1975)

device for internal combustion engines that converts pollutants in exhaust into less harmful molecules

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scrubbers

remove particulates and/or gases from industrial exhaust streams

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Wet scrubbers

generally the most appropriate device for collecting both particulate and gas in a single system

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Dry scrubbers

dry reagents are sprayed into an exhaust stream

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Desulfurization

Reduce SO2 emissions

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