Ch 18-19 Rxns
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105 Terms
Product?
Reagents?
directing group?
ortho/para director, weakly deactivating
mechanism?
EAS
Conditions/Notes
Phenols and anisoles over-halogenate
Product?
Reagents?
Directing group?
meta director, strongly deactivating
Mechanism?
EAS
Notes/Conditions?
Aniline cannot be nitrated
Product?
Reagents?
Directing group?
Meta director, strong deactivating
Mechanism?
EAS
Conditions?
Only adds para when added to a ring with an ortho/para director
Product?
Reagents?
Directing group?
meta director, moderately deactivating
Mechanism?
EAS
Conditions/Notes
Friedel-Crafts Acylation cannot occur with a meta director or NH2 on the ring
Product?
Reagents?
Directing Group
Ortho/para director, weakly activating
Mechanism?
EAS with carbocation rearrangements
Conditions/Notes
Friedel-Crafts alkylation, cannot occur with a meta director or NH2 on the ring, benzene rings must be in excess
Product?
Reagents?
Directing group?
Ortho/para director, weakly activating
Mechanism?
EAS with carbocation rearrangements
Conditions/Notes
Friedel-Crafts alkylation without a catalyst cannot occurs with a meta director or NH2 on a ring, benzene rings must be in excess
Products?
Reagents?
Mechanism?
NAS
Conditions/Notes?
Nu is often -OR or -NH2, requires a NO2 or a carbonyl ortho or para to the good leaving group (a halide)
Products?
Reagents?
Mechanism?
Reduction
Reaction name?
Wolff-Kishner Reduction
Product?
Reagents?
Mechanism?
Reduction
Reaction Name?
Clemmensen Reduction
Product?
Reagents?
Mechanism?
Reduction
Notes
Also reduces nonaromatic pi bonds
Products?
Reagents?
Mechanism?
Reduction
Notes?
Special for nitriles
Products?
Reagents?
Mechanism?
Organometallic Reactions
Rxn Name?
Suzuki Rxn
Products?
Reagents?
Mechanism?
Organometallic Reaction
Rxn name?
Gilman reagents/organocuprates
Products?
Reagents?
Products?
Mechanism?
Radical Reactions
Products?
Reagents?
Mechanism?
Substitution or Elimination
Conditions?
Mechanism depends on conditions
Products?
Reagents?
Mechanism?
Elimination, E2 (Hoffman)
Products?
Reagents?
Mechanism?
oxidation of alkyl side chains
Conditions/Notes
Requires a benzylic hydrogen (not quaternary Carbon)
Reagents?
Products?
Notes/Conditions?
Formation of diazonium salts from aniline
Products?
Reagents?
Notes?
Replacement of a diazonium salt with Cl
Products?
Reagents?
Notes?
Replacement of a diazonium salt with Br
Products?
Reagents?
Notes?
Replacement of a diazonium salt with CN
Reagents?
Products?
Notes?
Replaces diazonium salt with I
Products?
Reagents?
Notes?
Replaces a diazonium salt with F
Products?
Reagents?
Replacement of a diazonium salt with OH
Products?
Reagents?
Replacement of a diazonium salt with H, “removal” of the group from benzene
Reagent?
Any EAS mechanism
Product?
Directing group?
Follow the chart
Note 
Flashcards (50)