bond enthalpies

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6 Terms

1
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define mean bond enthalpy:

enthalpy (change) to break 1 mol bonds (in gaseous state)

2
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why must a bond enthalpy be in the gaseous state?

so all energy goes into breaking bonds and not changing state

3
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why might a calculated bond enthalpy be different to a bond enthalpy found in a data book?

  • bond enthalpies in data books are mean values taken from a range of compounds containing the specified bond - not the same as actual bond enthalpies

  • (if using calorimetry) values from bond enthalpy data ignore E changes in vaporisation of the fuel/condensing the water

4
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what is the general equation for bond enthalpies?

ΔH = bonds broken - bonds formed

5
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is bond breaking an exothermic or endothermic process? why?

endothermic - energy is required

6
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is bond making an exothermic or endothermic process? why?

exothermic - energy is released