ch12 rxns

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13 Terms

1
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alcohol + Na/THF + X-CH3

ether (alcohol)

2
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alkene + alcohol + Hg(oAc)2 + NaBH4/NaOH

ether (alkene)

3
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2x primary alcohol + H2SO4

ether (2x primary alcohol)

4
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tertiary alcohol + EtOH + H2SO4

ether (tertiary alc)

5
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alkene + mCPBA/benzene

epoxide

6
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alkene + Br/H2O + base/NaOH

epoxide

7
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ether + strong acid

cleavage of ethers

8
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epoxide + oEt/HoEt

opens epoxide

OH on more substituted

oET on less substituted

9
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epoxide + CH3OH/H2SO4

opens epoxide

OH on less substituted

oET on more substituted

10
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ethylene oxide (ch2-o-ch2) + gringnard reagent + ether,heat/H3O+

opens epoxide

11
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epoxide + h2o/catH+

trans-glycol

12
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alkene + OsO4/H2O

glycol

13
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glycol + H5IO6

cleavage of glycols