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Energy
capacity to cause change or do work, ability to rearrange matter
Potential energy
Based on structure and position relative to a field, not motion, bonds hold PE b/c if you break them it allows the molecules to move which = KE
Kinetic Energy
Movement of stuff, moving molecules = thermal E, moving photons = light E, and moving electrons = electricity, can be at the molecular level or visual level
Most energy comes from where
the sun
Chemical cycling
organisms live, die, return to the earth and become nutrients/energy for other organisms
Energy Flow
Energy moves through a food chain, doesn’t cycle, finally leaves as heat, passes through living systems
1st Law of thermodynamics
Energy cannot be created nor destroyed, only transformed
2nd Law of thermodynamics
When energy is transformed, entropy or disorder increases, transformations are not 100% efficient, some E is always given off as heat
Disorder
an increase in the movement of something that’s been broken up (changes in organization like a molecule), makes it more messy
How entropy can increase or decrease as a result of a system
During energy transformations the amount of energy available to do work decreases, what is lost comes off as heat, during anabolism, things energy is used to form bigger molecules, so there is less smaller things(less mess), so less entropy
What are the 2 main sources of potential energy in cells?
Bonds: usually weak covalent bonds and Concentration gradients: become potential when things start going across the membrane
Breaking bonds
releases energy
Molecules with very stable arrangement of orbitals have how much chemical energy?
very little, it is favorable to keep stable things as stable things, so we don’t break them up for energy
Spontaneous reactions
energy releasing, catabolic, favor more entropy because they are breaking up things into smaller things and making it more disorderly, ex. Diffusion b/c it decreases organization
More entropy equals …
smaller molecules, fewer bonds, less organization, less PE, and MORE ENTROPY
Less entropy equals …
Larger molecules, more bonds, more organization, more PE and LESS ENTROPY
Nonspontaneous reactions
absorb energy in order to occur
Ex. an inner and outer membrane not at equilibrium
Higher potential E b/c stuff wants to move down the gradient which creates kinetic energy once they move, while unequally distributed = more organized
Ex. an inner and outer membrane at equilibrium
Lower potential E b/c stuff doesn’t want to move down the gradient so things already have kinetic E, while unequally distributed = more organized
Ex. If things move against the concentration gradient
it is a nonspontaneous reaction b/c it requires the input of E
Photoautotrophs
Energy from sunlight and form their own organic molecules from (get Carbon from) inorganic molecules like CO2, ex. Plants
Photoheterotrophs
Energy from sunlight and get carbon from organic molecules, ex. specific types of bacteria, like heliobacteria
Chemoautotrophs
Get their energy from chemical compounds and get carbon from inorganic sources like CO2, ex. specific type of bacteria like Hydrogen bacteria
Chemoheterotrophs
Get their energy from chemical compounds and their carbon from organic compounds, ex. most bacteria and animals
Metabolism
all chemical reactions in an organism that convert molecules and transfer energy
Catabolism
break down molecules into smaller units; releases energy; hydrolysis
Anabolism
Build molecules from smaller units; requires energy input, dehydration synthesis
What is carbon for?
Building living things
Exergonic chemical reactions(spontaneous)
release energy, products have less free energy(more entropy) than reactants, negative delta G
Endergonic chemical reactions(nonspontaneous)
need an input of energy, products have more free energy(less entropy) than reactants, positive delta G
Energy Coupling reactions
catabolism(exergonic) and anabolism(endergonic) reactions happen together, the release of free energy from the exergonic reaction fuels the endergonic reaction
What is the chemical structure of ATP
Adenine, a five carbon ribose sugar and three phosphate groups bounded to the sugar
Where does ATP get most of its energy
the 3rd phosphate group, going from ATP to ADP + P is endergonic, using hydrolysis, ATP is continually recycled
What does phosphorylation mean?
adding a phosphate group, which is endergonic
What does dephosphorylation mean?
loosing a phosphate group
How does ATP help energy coupling
ATP facilitates energy coupling, breaking ATP(exergonic) and using that energy to power endergonic reactions (makes them favorable)
How does ATP cycle within a cell?
Making ATP is endergonic, it cycles by being made into ATP from ADP + P being broken and sending that energy into making other molecules or break molecules into their sub units
Transition state
unstable things with potential energy are used as activation energy which results in a jump of energy at the beginning of a reaction
If two reactions have different activation energies but the same resulting product energy, is the change in free energy different?
No, after activation energy is inputted that energy is then given off and then the energy from the intended reaction gives off energy, so the input of activation every is offset by the energy it gives off