Organic Chemistry Lecture Notes Review

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Flashcards created from lecture notes covering key organic chemistry concepts and reactions.

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20 Terms

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Croup

A branch of organic chemistry concerned with carbon-containing compounds.

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Hydrohalogenation

A reaction in which a hydrogen halide (HX) is added to an alkene.

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Markovnikov's Rule

States that in the addition of HX to an alkene, the hydrogen atom adds to the carbon with the most hydrogens.

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Hydration

The addition of water (H2O) across a double bond, converting alkenes to alcohols.

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Rearrangement

A process where the structure of a molecule is changed to form a more stable compound, often involving the migration of atoms.

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Hydroboration-Oxidation

A two-step process that converts alkenes to alcohols through a hydroboration step followed by oxidation.

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Catalytic Hydrogenation

The addition of hydrogen (H2) to an unsaturated hydrocarbon in the presence of a catalyst, converting it to an alkane.

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E1 Reaction

A unimolecular elimination reaction where the leaving group departs before the nucleophilic attack.

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Dihydroxylation

The addition of two hydroxyl (OH) groups to an alkene, resulting in a diol.

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Ozonolysis

A reaction in which ozone (O3) cleaves double bonds, resulting in the formation of carbonyl compounds.

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Radical

A highly reactive species with an unpaired electron.

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Epoxide

A cyclic ether with a three-membered ring, formed by the reaction of alkenes with peroxy acids.

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Acetal Formation

A reaction where aldehydes or ketones react with alcohols under acidic conditions to form acetals.

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Friedel-Crafts Acylation

A reaction that introduces an acyl group (RCO-) onto an aromatic ring using an acyl chloride and a Lewis acid.

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Wittig Reaction

A chemical reaction used to convert carbonyl compounds into alkenes through the reaction with phosphonium ylide.

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Radical Polymerization

A method of polymerization that involves radical initiation and the repetitive addition of monomers.

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Grignard Reaction

A reaction where organomagnesium reagents react with carbonyl compounds to form alcohols.

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Chromic Acid Test

A test to determine the presence of primary alcohols, secondary alcohols, and aldehydes through oxidation.

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Tollens Test

A chemical test used to detect aldehydes by producing a silver mirror.

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Lucas Test

A test to differentiate between primary, secondary, and tertiary alcohols by reactivity with Lucas reagent (HCl + ZnCl2).