Reaction Mechanisms
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O chem
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8 Terms
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Nu = X or OH
double bond attacks H
Markovnikov addition - not stereospecific
Anti-Markovnikov with H2O2
racemic mix
2
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Anti-Mark addition
Form cyclic intermediate ion
trans-aklene = meso comp
cic-alkene = pair of enantiomers
(if reacting with H2O, O is more electronegative thus attaches to more highly substituted C because it has a more positive charge)
3
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Cyclic intermediate
syn addition
Markovnikov addition
not controlled stereochem.
4
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cyclic intermediate
anti- markov addition
syn addition
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Syn addition of two OH groups
Mix of enantiomers
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di sub = ketone
mono sub = carboxylic acid
uni sub = CO2
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di sub = ketone
mono and uni sub = aldehyde
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cis alkene = cis alkane
trans alkene = trans alkane
Note 
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