Adv Chem - Acid Base Equilibrium

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49 Terms

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Arrhenius definition of acids

Acids react with water to form H3O+

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Strong acid

An acid that completely dissociates in water

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Strong acid

HCl (strong or weak)

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Strong acid

HClO4

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Strong acid

HClO3 (strong or weak)

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Strong acid

HBr

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Strong acid

HI

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Strong acid

H2SO4 (strong/weak)

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Strong acid

HNO3 (strong or weak)

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Weak acid

An acid that partially ionizes in water

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Monoprotic

An acid that can donate one proton

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Monoprotic acid

HCl

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Monoprotic acid

HNO3

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Polyprotic

An acid that can donate more than one proton

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Polyprotic acid

H2SO4

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Polyprotic acid

H3PO4

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Arrhenius definition of bases

Base solutions reacts with water to produce OH-

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Strong bases

A base that is soluble in water and completely disassociates in water

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Strong base

NaOH

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Strong base

KOH

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Weak base

A base that partially dissociates in water

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Weak base

NH3

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Weak base

NaHCO3

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Weak base

NaCO3

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Problems with Arrhenius definition

- limited to aq solutions
- doesn't classify chemicals that sometimes act as acid, sometimes act as base

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Bronsted Lowry

Acids: Proton (H+) Donors
Bases: Proton (H+) Acceptors

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On the right side with the products

Where are conjugate acid/base placed in an equation?

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Amphiprotic

A species that can either accept or donate a proton and can act either as an acid or a base

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Titration

A chemical technique used to determine the concentration of a solution

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Indicator

A chemical compound used to signal the end of a titration

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End point

The point in a titration at which an indicator changes color

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Equivalence point

The point in a titration where the number of moles of hydrogen (H+) ions equals the number of moles of hydroxide (OH-) ions

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Buffers

Solutions that resist change in pH

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Strong acid that dissociates more in water

High Ka:

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weak acid

Low Ka:

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pH

The measure of the hydrogen ion (H+) concentration of a solution

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pOH

The measure of the OH- concentration in a solution

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pH equation

-log[H+]

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pOH equation

-log[OH-]

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14

Basic on pH scale

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1

Acidic on pH scale

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7

Neutral on pH scale

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Weak conjugate

A strong acid/base (type of conjugate)

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Weak conjugate

weak acid/base (type of conjugate)

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Strong conjugate

Feeble acid/base (type of conjugate)

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14

pH + pOH =

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1.00*10^-14

Kw constant

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[H3O+][OH-]

Kw factors

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By mixing the salt that contains the conjugate base/acid of the weak acid/base

How are buffers created?