Difference between Chlorination & Bromination

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10 Terms

1
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The first step of the propagation step is _________ in both cases

rate determining

<p>rate determining</p>
2
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If X=Cl → _____

exothermic

3
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If X=Br → ______

endothermic

4
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<p>-_______ is faster than _______</p><p>-Chlorination ______ regioselective &amp; forms a mixture of chlorinated products, while bromination yeilds __________ brominated product</p>

-_______ is faster than _______

-Chlorination ______ regioselective & forms a mixture of chlorinated products, while bromination yeilds __________ brominated product

-chlorination, bromination

-is not, one major

<p>-chlorination, bromination</p><p>-is not, one major</p>
5
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Reactivity-selectivity principle: less negative reagents are ______ selective

more

6
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7
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8
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9
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<p>Halogenation of an achiral S.M&gt; generates a _________ mixture of _______</p>

Halogenation of an achiral S.M> generates a _________ mixture of _______

racemic, enantiomers

<p>racemic, enantiomers</p>
10
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<p>Halogenation of a stereogenic center leads to the _______ of that stereogenic center</p>

Halogenation of a stereogenic center leads to the _______ of that stereogenic center

racemization

<p>racemization</p>