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superimposable
line up and match perfectly in 3D shape. identical
enantiomers
non superimposable. mirror images. identical physical properties except rotate plane of polarized light opposite direction. different biological biochemical properties
diastereomers
enantiomers times 2 or 3 or 4 etc. 2 or more chiral centers. don’t have identical physical properties. part identical part mirror image
chiral center
atom with 4 or more different groups attached
R configuration
clockwise
S configuration
counterclockwise