Preparation of Halogenoalkanes
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4 Terms
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Free radical substitution of alkanes
Reagents: X2 gas (X=Cl2 or Br2)
Conditions: UV light
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Electrophilic Addition to Alkenes
Addition Of HX(g) (dry HX, rtp)
Addition of X2 (X2 in CCl4, rtp, absence of UV light)
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Free Rad Subst VERSUS Electrophilic Addtion, which will give a higher yield of products?
Free radical is less suitable as the substitution of H atoms is random, causing a mixture of products to be formed.
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Nucleophilic Substitution Of Alcohols By Halogens
HCl & heat
anhydrous PCl5, rtp
HBr
HI
Note 
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