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9 Terms

1
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Consider this equilibrium:

2SO2(g) + O2(g) ~ 2S03(g)
The forward reaction is proceeding at a certain rate at some temperature and pressure. When the pressure is increased, what might we expect for the forward reaction?

a greater rate of reaction and a greater yield of S03 at equilibrium

2
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The Arrhenius equation describes the relationship between the rate constant, k, and the energy of k -- Ae-Ea/RT

activation, Ea.
In this equation, A is an empirical constant, R is the ideal-gas constant, e is the base of natural logarithms, and Tis the absolute temperature. According to the Arrhenius equation,

at constant temperature, reactions with lower activation energies proceed more rapidly.

3
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What will be the effect of increasing the temperature of reactants that are known to undergo an endothermic reaction?

Both the rate ofreaction and the value ofthe equilibrium constant increases.

4
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The change in temperature from I0 °C to 20 °C is found to double the rate of a particular chemical reaction. How did the change in temperature affect the reaction?

The number o f molecules with sufficient energy to react increased.

5
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The value for the rate constant ofa reaction can generally be expected to

increase with increasing temperature.

6
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Two reactions with different activation energies have the same rate at room temperature. Which statement correctly describes the rates o f these two reactions at the same, higher temperature?

The reaction with the larger activation energy will be faster.

7
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A catalyst increases the rate of a reaction by

changing the mechanism of the reaction.

8
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Which statement most accurately describes the behavior of a catalyst?

A catalyst reduces the activation energy for a reaction and increases the rate of a reaction.

9
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The rate law for the reaction A+B---->C+D

is first order in [A] and second order in [B]. If[A] is halved and [B] is doubled, the rate of the reaction will

be increased by a factor of 2.