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radius ratio < 0.225
coord = 3, trig planar
radius ratio = 0.225 → 0.413
coord = 4, tetrahedral
radius ratio = 0.414 → 0.731
coord = 6, octahedral
radius ratio = 0.732 → 0.999
coord = 8, cubic
radius ratio = 1
coord = 12, close-packed

Rock Salt
CCP Anions, octahedral holes filled, coord = 6

CsCl
Primitive Cubic Array Anions, coord=8

NiAs
HCP (distorted) Anions, Octahedral holes filled, coord=4

Wurztite
HCP anions, ½ tetrahedral holes, coord=4

Zinc Blende (ZnS) also known as Sphalerite Structure
CCP anions, ½ tetrahedral holes filled, coord=4