solids

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28 Terms

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kinetic molecular theory of solids

forces of attraction lock molecules in place

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what movement occurs in solids

vibratino

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2 types of solids

  1. crystalline

  2. amorphous

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crystalline solids

particles are in hgihly ordered arragnemtn

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crystalline lattice

repeating pattern of particles

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amorphous solids

made up of randomly oriented atoms, ions or molecles that don’t form a definite pattern/lattice structure

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properties of amorphous solids

no definite set of properties

parts of them can differ from the rest (ex. parts of glass have diff melting temps)

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types of crystalline soldis

  1. covalent netowkr solids

  2. ionic solids

  3. metallic solids

  4. molecular solids

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covalent netowkr solids characteristics

hard, high mp

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examples of covalent netowrk solids

diamond, SiO2 (sand and quartz), SiC

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formatting of covalent netowrk solids

contain no discrete molecular unit

atoms in network solid held tg by covalent bonds with neighboring atoms

single extended netowkr

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allotropes

different forms fo thesame elementt htat differ in bonding

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example of allotropes

diamond, graphite, buckyball

O2, O3

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ionic solids

ions held tg by strong electrostatic attraction

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what does melting point of ionic solids depend on

magnitude of lattice energy (charge+size of ions)

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electrolytes

soluble ionic compounds whose water solution conducts electricity

contains free moving ions

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metallic solids

covalent bonds between and ions in a sea of delocalized valence electrons

hardness and mp depend on number of valence electrons

wide range

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molecular solids

molecules held tg by weak IMF (dipole ddipole, LDF, h-bond)

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properties of molecular solids

soft, low mp (usually below 200 C)

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like dissolves like

things dissolve based on polarity

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non-electrolytes

ubstances whose water solutiosn do not conduct electricity bc no dissasociated ions

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acids

molecular substances that form ions when dissolved in water

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alloys

mixtures of metals with other elements, either metal or non metal

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2 outcomes for alloys

substitutional solid

interstitial solid

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substitutional solid

some metal atoms replaced by others of similar size

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interstitial solid

added atoms squeeze between most atoms

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example of interstitial solid

steel

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