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when do chemical reactions occur
when atoms have sufficient energy to combine or change their bonding partners to form new substances
energy
capacity to do work/change
forms of energy
chemical, electrical, heat, light and mechanical
chemical energy
doesn’t do work but has potential to do so e.g. energy stored in chemical bondsthat can be released during a chemical reaction.
electrical energy
separation of charges (electrical gradients), capable of doing work
heat energy
transfer due to temp differences and does work
light energy
electromagnetic radiation stored in photons
mechanical energy
energy of motion, does work
potential energy
stored energy due to position or state, can be converted to kinetic energy. e.g in bonds
kinetic energy
energy of movement - the type that does work/makes changes
anabolic reactions
simple molecules linked to form complex ones - requires energy and captures it in chemical bonds formed (potential energy)
catabolic reactions
complex molecules broken down into simpler ones - energy released
1st law of thermodynamics
energy is neither created nor destroyed = energy is constant so can be transferred and transformed
open system
energy and matter can be transferred between the system and its surroundings - organisms are open systems
closed system
isolated from its surroundings
2nd law of thermodynamics
disorder tends to increase - energy transfer/transform increases entropy as when transformations of energy occurs some energy is lost or unusable
in bio systems energy is lost as heat
entropy
measure of disorder in a system
change in free energy (G) equation
ΔG = ΔH - TΔS
G = free energy
H = total energy
T = temperature in Kelvin
S = entropy
Δ = change
endergonic reactions
needs input of energy to happen results in positive change in free energy (ΔG > 0). - anabolic
exergonic reactions
release energy, resulting in a negative change in free energy (ΔG < 0). - catabolic