Ch03_Alkanes___their_stereochemistry

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39 Terms

1

Alkanes

A class of saturated hydrocarbons with the general formula CnH2n+2, containing only C–C and C–H single bonds.

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2

Isomers

Compounds that have the same chemical formula but different structures.

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3

Constitutional Isomers

Isomers that differ in the connections between atoms, such as butane and isobutane.

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4

Functional Groups

Groups of atoms within a larger molecule that have characteristic chemical reactivity.

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5

Torsional Strain

The extra energy present in eclipsed conformations due to the repulsive interactions between bonding orbitals.

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6

Branched-Chain Alkanes

Alkanes where the carbon atoms are arranged in a branched fashion rather than a continuous chain.

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7

Straight-Chain Alkanes

Alkanes with all carbon atoms connected in a row.

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8

Staggered Conformation

A conformation where the bonds in a molecule are as far apart as possible, reducing energy.

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9

Eclipsed Conformation

A conformation where bonds are as close as possible, resulting in higher energy due to torsional strain.

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10

Newman Projections

A method of visualizing the spatial orientation of a molecule by looking along a carbon-carbon bond.

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11

Alkyl Groups

Partial structures that result from removing a hydrogen atom from an alkane, used as substituents in larger compounds.

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12

Saturated Hydrocarbons

Hydrocarbons that contain the maximum number of hydrogen atoms per carbon atom, with only single bonds.

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13

Dispersion Forces

Weak intermolecular forces between molecules that increase with molecular size and affect melting and boiling points.

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14

Alcohol

Organic compounds that contain one or more hydroxyl (-OH) functional groups, which are derived from hydrocarbons.

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15

Aldehyde

Organic compounds that contain a carbonyl group (C=O) bonded to at least one hydrogen atom, typically represented by the formula RCHO, where R is a hydrocarbon group.

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16

Aliphatic

A type of organic compound characterized by straight or branched-chain structures, which can be saturated (alkanes) or unsaturated (alkenes and alkynes).

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17

Alkene

A class of unsaturated hydrocarbons that contain at least one carbon-carbon double bond (C=C), with the general formula CnH2n.

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18

Alkyl Halide

Organic compounds containing a carbon atom bonded to a halogen atom (F, Cl, Br, I). They are derived from alkanes by replacing one or more hydrogen atoms with halogen atoms.

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19

Alkyne

A class of unsaturated hydrocarbons that contain at least one carbon-carbon triple bond (C≡C), with the general formula CnH2n-2.

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20

Amide

A functional group characterized by a carbonyl group (C=O) directly attached to a nitrogen atom (N). Amides are derived from carboxylic acids by replacing the -OH group with an -NH2 (or similar) group.

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21

Amine

Organic compounds that contain a nitrogen atom bonded to one or more alkyl groups. Can be classified as primary, secondary, or tertiary depending on how many carbon groups are attached to the nitrogen.

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22

Anti Conformation

A conformation in which substituents on a carbon-carbon bond are positioned 180 degrees apart, resulting in the lowest steric strain.

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23

Arene

A class of cyclic hydrocarbons that contain one or more aromatic rings, characterized by alternating double bonds and stabilized by delocalized π-electrons.

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24

Carbonyl Group

A functional group characterized by a carbon atom double-bonded to an oxygen atom (C=O), found in aldehydes, ketones, carboxylic acids, and amides.

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25

Carboxylic Acid

Organic compounds that contain a carboxyl group (-COOH), which consists of a carbonyl group (C=O) and a hydroxyl group (-OH) attached to the same carbon atom.

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26

Conformation

The specific three-dimensional arrangement of atoms in a molecule, resulting from rotation about single bonds.

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27

Conformational Isomer

Isomers that differ in the arrangement of atoms and their spatial orientation due to rotation about single bonds.

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28

Conformer

Different spatial orientations of a molecule that can be interconverted by rotating around single bonds.

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29

Ester

Organic compounds formed from the reaction of an alcohol and a carboxylic acid, characterized by a carbonyl group (C=O) adjacent to an ether (-O-) group.

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30

Ether

Organic compounds containing an oxygen atom bonded to two alkyl, with the general formula R-O-R'.

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31

Gauche Conformation

A conformation in which two substituents on a carbon-carbon bond are positioned 60 degrees apart, resulting in increased steric strain.

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32

Hydrocarbon

Organic compounds consisting entirely of hydrogen and carbon atoms, which can be saturated or unsaturated.

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33

Ketone

Organic compounds that contain a carbonyl group (C=O) bonded to two carbon atoms, typically represented by the formula R1-CO-R2.

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34

Nitrile

Organic compounds that contain a cyano group (-C≡N), characterized by a carbon atom triple-bonded to a nitrogen atom.

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35

R Group

A variable group in organic chemistry that represents a hydrocarbon or functional group attached to a molecule's core structure.

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36

Saturated

Refers to organic compounds that contain the maximum number of hydrogen atoms per carbon atom, with only single bonds present.

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37

Sawhorse Representation

A three-dimensional representation of a molecule that allows visualization of the spatial arrangement of atoms by depicting the conformation along a carbon-carbon bond.

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38

Stereochemistry

The study of the spatial arrangement of atoms in molecules and their effects on the chemical and physical properties.

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39

Steric Strain

The increase in energy that occurs when atoms in a molecule are forced closer together than their natural distances, often due to large substituents.

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