Fundamentals of Amines and Amides

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21 Terms

1
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What is the amine functional group

NH2

2
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How to prepare an Amine from halogenoalkane

Heat

Excess NH3 (ethanolic)

3
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4
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What is the classifaction as primary, secondary or tertiary amines based on

based on the number of carbons bonded directly to the nitrogen.

Primary - 1 carbon

Secondary - 2 carbons

Tertiary - 3 carbon

5
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what is aromatic amine.

If a benzene is directly bonded to the nitrogen in an amine group

6
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what is an aliphatic amine. 

if not benzene is directly bonded to the nitrogen in an amine group,

7
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Ammine + Acyl Chloride

Amide

<p>Amide</p>
8
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Ammine + Acid anhydride

Ammide

<p>Ammide</p>
9
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How ammides classifies

classify them based on the number of carbons bonded to the nitrogen.

10
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Name ammine at end of chainf

root,ylamine

11
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name tertiary ammine at end of chain

add approapate multiperler, root ylamine

12
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name if ammine is not in the end of chain

root-an-position number-amine

lower prority group added to prefix as usual

13
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what if ammine is not highest priorty

use prefix amino

14
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name a primary amide

root-an - amide

15
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naming a tertiary amide

group withot carbonyl group as subsituent

name of main chain add substient as pefix, with N before it, to show boned with nitrogen

16
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name a teritary amide with identical substeints

add multiepr before perfix and inclued N,N before

17
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name a tertiarty amide with diffrent substients

order substients in alphabetical order include N before each susbtient

18
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what bond can Primary and secondary amines and amides form

can form hydrogen bonds to other primary and secondary amines and amides. This is because they have an N-H bond, with a lone pair on the nitrogen. 

19
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what do all amides and amines form with water

all amines and amides can form hydrogen bonds with water molecules

20
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solubility of amines amides

all amines and amides can form hydrogen bonds with water molecules

This means that small amines and amides are highly soluble in water; their solubility decreases as the size of the molecule increases.


21
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why can amines act as nucelophiles and electrophiles

because amines have a lone pair of electrons,