bond enthalpies

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4 Terms

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what is average bond enthalpy?

  • energy required to break one mole of specified type of bond in gaseous molecule

  • bond enthalpies are always endothermic therefore they have positive enthalpy value

2
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bond breaking and making…

  • endothermic: energy required to break bonds; delta H is positive

  • exothermic: energy released when bonds form; delta H is negative

<ul><li><p>endothermic: energy required to break bonds; delta H is positive</p></li><li><p>exothermic: energy released when bonds form; delta H is negative</p></li></ul>
3
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calculating enthalpy changes from average bond enthalpies…

  • for a reaction involving gaseous molecules of covalent substances: reactants - products

  • actual energy involved in breaking/making individual bonds is slightly different

<ul><li><p>for a reaction involving gaseous molecules of covalent substances: reactants - products</p></li><li><p>actual energy involved in breaking/making individual bonds is slightly different </p></li></ul>
4
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what is Hess’ Law?

  • states that if reaction takes place by two routes, and starting and finishing conditions are same, total enthalpy change is same for each route

<ul><li><p>states that if reaction takes place by two routes, and starting and finishing conditions are same, total enthalpy change is same for each route</p></li></ul>