reagents for acylation

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17 Terms

1
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carboxylic acid to acid chloride

socl2 5 steps

2
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carb acid to thioester

hsch3 + tsoh 6 steps

3
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carb acid to ester

hoch3 + tsoh 6 steps

4
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carb acid to acid anhydride

carb acid + heat 6 steps

5
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carb acid to carboxylate

strong base 1 step

6
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CAD to carb acid

h2o + acid or base

7
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carboxylate to carb acid

acid

8
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CAD to acid anhydride

carb acid

9
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CAD to thioester

hsch3 + acid or nasch3 + hsch3

10
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CAD to ester

hoch3 + acid or hoch3 & naoch3

11
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CAD to amide

HN(ch3)2 + base

12
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ways to make carb acids

  1. O3 2. h2o2 from double bond

  2. cro3, h2o, h2so4 from primary alc or aldehyde

  3. 1. CO2 2. h3o+ from carbon nuc with Li +

  4. ag2o + h2o, mcpba (RC=OOOH) from aldehyde

  5. CAD with h2o + acid or base

13
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carb acid to acid chloride steps

5 steps: carb =o is nuc and attacks socl2, 2.

14
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17
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