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Last updated 7:08 PM on 4/5/26
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6 Terms

1
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Triple/Double Bond Reduction

  • Pd/C H2

  • Lindlars H2 (partial reduction of triple bonds)

  • Rh(P(Ph)3)Cl (selective: wont reduce tetra subbed)

2
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Heck Reaction (Linking two sp2 carbons)

  • Pd(OAc)2 Cat. P(Ph)3 BINAP

  • Needs leaving group on one

3
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Suzuki-Miyara Reaction (Replacing Borohydrate group)

  • Similar to heck

  • Need a good leaving group on one

4
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Organometallics

  • Much like grignard but with Li instead

5
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Cuprate

  • (R)2CuLi

  • Will only add one time unlike grignard

6
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Wittig

  • only works for keytone and aldehydes

  • replaces C=O with whatever R=P(Ph3) → C=R

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