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17 Terms

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Entropy

A measure of the dispersal of energy in a system

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Standard Enthalpy Change of Reaction

The enthalpy change when the reactants in the stoichiometric equation react to give the products under standard conditions

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Standard Enthalpy Change of Formation

The enthalpy change when one mole of a compound is formed from its elements under standard conditions.

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Standard Enthalpy Change of Combustion

The enthalpy change when one mole of a substance reacts completely with oxygen under standard conditions

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Standard Enthalpy Change of Neutralisation

The enthalpy change when one mole of water is formed by reacting an acid and alkali under standard conditions

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Lattice Enthalpy

The energy change when one mole of an ionic compound is formed from its gaseous ions under standard conditions.

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Enthalpy change of Atomisation

The enthalpy change when one mole of gaseous atoms are formed from the element in its standard state.

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First ionisation energy

The energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions.

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First electron affinity

The enthalpy change that takes place when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions.

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Mole

The amount of substance containing as many particles as there are carbon atoms in exactly 12g of the carbon-12 isotope.

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Definition of Electronegativity

The relative tendency of an atom in a covalent bond in a molecule to attract electrons in a covalent bond to itself.

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Definition of Complex Ion

A transition metal ion bonded to 1 or more ligands by dative covalent bonds

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Definition of Ligand

A molecule or ion that can donate a pair of electrons to a transition metal to form a dative bond.

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Definition of Co-ordination number

The total number of dative bonds formed between a central metal ion and its ligands

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Definition of Ligand substitution

One ligand replacing another

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Definition of stereoisomerism

Same molecular formula, but a different arrangement in 3D space

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Definition of Cis/Trans Isomers

Isomers formed when there are 2 different R groups bonded to each C of a C=C, which is unable to rotate, specifically when each carbon contains the same 2 groups of atoms