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Describe the significance of the octet rule in covalent bonding
Atoms tend to bond to have eight electrons in valence shell, achieving stability
Define a dipole moment
Measures polarity of a molecule, larger dipole means more polar
Explain what a covalent bond is
Formed when two atoms share electrons, counting shared electrons in valence she
What determines the melting points of ionic substances?
Ion charge and ion size influence melting points, greater charge and smaller size lead to higher melting points
Distinguish between electronic geometry and
molecular geometry
Electronic geometry considers all electron
pairs, molecular geometry considers only
bonded atoms
How to determine molecular geometry using
VSEPR theory?
Draw Lewis structure, count electron-dense
regions, arrange to minimize repulsive
Define alloy
Mixture of elements with metallic properties, can be substitutional or interstitial based on atom sizes
Define sigma (σ) and pi (π) bonds
Sigma bonds are first bonds formed, pi bonds formed in addition to sigma in double and triple bond
Explain how ionic solids conduct electricity
do not conduct electricity, electrons localized, ionic liquids conduct as ions free to move
Define an ionic bond
formed when cation donates electrons to anion, creates electrostatic forces binding ions together
Describe formal charges in Lewis structure
represent charge of an atom, ideally small, favoring 0 for stability
What is lattice energy?
bond energy in ionic bonds, increases with charge of ions, according to Coulomb's La
Explain VSEPR theory
electron pairs repel each other, determines molecular geometry, based on bonding and nonbonding paiRs
Describe a polar covalent bond
Occurs when two atoms share electrons
unequally, results in partial charge
Explain the significance of hybridization in
chemistry
Mixing of atomic orbitals to form new hybrid
orbitals, determines shape and bonding
Define electronegativity
Ability of an atom to attract electrons in a chemical bond, influences bond polarity
What is the Lewis electron-dot symbol?
Represents an element's valence electrons using dots around the chemical symbo
Describe the N – A = S rule in Lewis
structures
Helps determine electron placement, N is electrons needed, A is available, S is shared
What are the properties of metals?
Tend to lose electrons easily, malleable, ductile, conduct electricity, shiny appearanc
How does the shape of a molecule relate to its electron pairs?
Determined by arrangement of electron- dense regions, can influence bonds and lone pairs
Distinguish between substitutional and interstitial alloys
Substitutional alloys have host metal atoms
replaced by similar-sized atoms, interstitial
alloys have smaller atoms in holes
Describe the polarity of water and its molecular structure
Polarity arises from unequal sharing of electrons, creating a dipole with negative oxygen and positive hydrogens
Explain the difference between ionic and metallic bonding
Ionic bonding involves electron transfer and charged ions, metallic bonding involves delocalized electrons among metal atom
Define bond length and bond energy
Bond length is the distance between bonded nuclei, bond energy is the strength of the bond
Describe the relationship between bond strength and bond order
Higher bond order corresponds to stronger and shorter bonds compared to single bond
Explain the role of lone pairs in molecular geometry
Lone pairs occupy space and exert repulsive forces, affecting molecular sha
Describe the role of delocalized electrons in metallic bonding
Delocalized electrons allow for conductivity and malleability, enabling movement throughout the metal lattice
Describe the effect of bond polarity on molecular interaction
Affects intermolecular forces, influences boiling and melting points, interactions between polar molecules
Define substitutional and interstitial alloy
Substitutional alloys replace host metal atoms with similar-sized atoms, interstitial alloys occupy spaces with smaller atoms
Explain how ionic liquids differ from ionic solids in conductivity
Ionic liquids conduct electricity due to free moving ions, ionic solids do not conduct due to localized electrons
What molecular geometry is associated with five electron pairs?
Trigonal bipyramidal molecular geometry
Describe hybridization and its types based on electron domains
Mixing of atomic orbitals, types include sp for 2 domains, sp2 for 3 domains, sp3 for 4 domain
How does the size of ions affect conductivity in ionic substances?
Smaller ions result in greater Coulombic attraction, affecting melting point and conductivitY
What type of bond is formed when atoms share electrons equally?
Nonpolar covalent bond
Describe the structure of a trigonal planar molecule
Three bonding pairs and no lone pairs, results in a flat, triangular shapE