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enthalpy change
heat energy change measured under conditions of standard pressure
standard enthalpy changes
standard conditions (100kPa, 298K)
bonds broken =
energy taken in
positive enthalpy change
bonds formed =
energy given out
enthalpy change is negative
overall enthalpy change =
energy to break bonds + energy to make bonds
enthalpy of formation
enthalpy change when one mole of a substance is produced from its elements under standard conditions
enthalpy of formation
enthalpy change when one mole of a substance is burned completely in oxygen under standard conditions
different covalent bonds →
different amount of energy required to be broken
bond enthalpy values vary by situation =
-data book values are average
-values found experimentally using calorimetry methods