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acids
pH < 7
release hydrogen
conduct electricity in solutions
binary acid
hydrogen and non-metal
aqueous
“hydro__-ic acid”
oxyacid
hydrogen, polyatomic
oxygen and non-metal are bonded to form a complex ion
adding or removing oxygens will make a new oxyacid
exception: acetic acid (CH3COOH) which comes from acetate (CH3OO), it doesn’t follow the normal rules
naming oxyacid
1 more oxygen = “per__ic acid”
main = “-ic acid”
1 less = “-ous acid”
2 less = “hypo__ous acid”
naming complex ions
1 more oxygen = “per__ate”
main = “-ate”
1 less = “-ite”
2 less = “hypo__ite”
peroixde
contain 1 more oxygen then the normal oxide
don’t reduce
to write formula: add 1 more oxygen
to name: add “per” in front of oxygen
oxyacid salt
metal, polyatomic ion w/oxygen
formula naming rules are the same
naming rules are the same, just add prefixes/suffixes if a oxygen is added/removed
acid salt
metal, hydrogen, polyatomic
naming rules: put a prefix in front of hydrogen and add prefixes/suffixes to polyatomic ion if oxygen is added/removed
acid salt anion: made when you add hydrogen to a polyatomic ion. the charge goes up by 1
base
pH > 7
release OH
conduct electricity in solutions
metal, hydroxide
exception:
some bases don’t have a OH, instead they have a bicarbonate ion
NH4OH is a base even though there’s no metal
hydrate
water bonded to a solid
naming is like other salts, at the end add “hydrate” with the prefix for the number of waters
write formula like other salts, after write a dot and H2O with the number in front
balancing combustion reactions
balance carbon first, hydrogen second, and oxygen last. you may need to double everything to get the proper oxygen number
mineral
solid substance found on earth, contain elements (ex: gold, copper silver)
ore
rock with high amount of a valuable element (ex: gold, copper)
precious metals
highly desired metals (ex: gold, silver)
base metals
not highly desired metals (ex: copper, nickel)
metallurgy
extracting metals from their ores and processing them into useful forms
a lot of rock needs to be mined/processed because most samples contain little of the valued material
the challenge is that they need to find an efficient way to do this
smelting
chemical process that extracts a metal from its ore using high heat and chemicals
what other elements are mixed in copper ore
iron and sulfur
why is sulfur dioxide gas harmful to the environment
it goes into the air and reacts with water in the clouds to make acid rain
what can be done with SO2 to prevent acid rain
scrubbers are installed in the furnace to trap it and turn it into sulfuric acid to sell. flash smelting is also used
what is made with copper
water pipes, wires, cables, electrical products
what do ontario smelters process
nickel-copper ore, lead, zinc
flash smelting
separates the metal by heating it to high temperatures with pure oxygen
it reduces fuel costs
it causes less pollution
positive effects of smelters
metals are sold internationally
creates jobs
makes lots of products
where are ontario smelters located
greater sudbury region
mississauga
scrubber
device installed in furnaces to prevent sulfur dioxide gas from escaping and makes it into a safer substance
what government regulations are there to protect the environment
stricter laws
companies need detailed environmental assessment to get permission
companies need plans for closure and rehabilitation
what types of air pollution do mining produce
dust
sulfur dioxide
what types of water pollution does mining produce
freshy exposed rock is prone to erosion which can create acid mine drainage. acid water can dissolve toxic substances which can then go into ecosystems
how to deal with acid mine drainage
neutralize acidity with calcium carbonate (in limestone)
synthesis
combining two substances to form a new compound
metal + oxygen synthesis
always makes a solid
makes a metal oxide
non-metal + oxygen synthesis
makes a non-metal oxide
metal + non-metal synthesis
makes a binary ionic compound
metal oxide + water synthesis
makes a base
always aqueous
non-metal oxide + water synthesis
makes oxyacid
exception: chloric acid (HClO3) is formed from hydrochloric acid (HCl) and oxygen gas
you don’t always balance
non-metal oxide + metal oxide synthesis
makes salt of an oxyacid
aka metal crossed with polyatomic ion ending in “ate”
exception: chlorates (metal-ClO3) are formed from chloride salts (metal-Cl) and oxygen
decomposition
breaking down a compound into two or more substances
has the same reaction types as synthesis
electrolysis for decomposistion
uses electrical energy to cause a chemical reaction
heat for decomposition
heat breaks down the chemical bonds of the compound (thermal decomposition)
catalyst
chemical that speeds up the reaction, its not apart of the reaction though
metal oxide decomposition
breaks into a metal and oxygen
non-metal oxide decomposition
breaks into a non-metal and oxygen
binary ionic compound decomposition
breaks into a metal and non-metal
base decomposition
breaks into a metal oxide and water
oxyacid decomposition
breaks into a non-metal oxide and water
memorize:
H2SO4 = SO3 + H2O
H2SO3 = SO2 + H2O
salt of an oxyacid decomposition
breaks into a non-metal oxide and metal oxide
exception:
metal chlorate = metal chloride + oxygen gas
KNO3 = KNO2 + O2
NaNO3 = NaNO2 + O2
hydrate decomposition
breaks into a ionic compound and water
single displacement
a reaction where one element takes the place of another
must use an activity series
metal displacing another metal from an ionic compound
A + BX = AX + B
A must be higher than B on the activity series
metal displacing hydrogen from an acid
A + HX = AX + H
treat hydrogen as a metal (its not)
treat H2SO4 as HHSO4
metal displacing hydrogen from water
A + H-OH = base + H
non-metal displacing another non-metal from an ionic compound
X + YZ = YX + Z
double displacement
reaction where the cations of two aqueous compounds switch places
one of the products must be either solid, gas, or water
must use solubility chart
double displacement that forms a precipitate
normal crossing of elements, use solubility chart to predict the states
double displacement that forms a gas
reaction that produces hydrogen gas
reaction that produces hydrogen sulfide gas
reaction that produces sulfur dioxide gas
creates sulfurous acid, which breaks down into water and sulfur dioxide
reaction that produces carbon dioxide
produces carbonic acid first, which breaks down into water and carbon dioxide
reaction that produces ammonia gas
when you mix a compound with ammonium and a compound with hydroxide, you get an ionic compound, ammonia gas, and water
double displacement that forms water
happens in neutralization
an ionic compound and water is produced
neutralization
acid and base are mixed together to create a solution with a pH of 7
creates an ionic compound and water
type of double displacement
neutralization with a hydroxide compound
the hydrogen ions from the acid and the hydroxide ions from the base react to make water
the left over ions make a ionic compound (salt)
common reaction
neutralization with a carbonate compound
produces carbonic acid which then decomposes into water and carbon dioxide
NaHCO3 (sodium hydrogen carbonate) aka baking soda can act as both an acid or base
what is acid reflux/heartburn
irritation of the esophagus by stomach acid
what is a short term fix for heartburn
antacid medication neutralizes the stomach acid
what is responsible for the acidification of ontarios lakes
emissions of sulfur oxide and nitrogen oxide from combustion of fossil fuels
why is acidification of lakes bad
organisms can’t handle the acidity
shells/coral breaks down
populations crash
why are northern lakes in onatrio more prone to damage from acid rain
the bottom of the lakes are made up of granite which is hard and not reactive so it can’t neutralize the lake, unlike lakes which have limestone at the bottom
liming a lake
adding calcium oxide (lime) to the lake to temporally neutralize acidity
how does baking soda rise dough
sodium hydrogen carbonate reacts with something acidic (like vinegar) and CO2 bubbles cause the dough to rise. the warmth of the oven makes the bubbles expand
3 factors when choosing neutralization reactant
safety
cost
chemical prosperities
why are sulfuric acid and sodium hydroxide not safe neutralizing agents
crossive
leaves left over residue
could splash
combustion of hydrocarbon
will burn in the presence of oxygen to produce oxides
a compound containng hydrogen and carbon (sometimes oxygen)
complete combustion
happens when there is sufficient oxygen
creates carbon dioxide, water vapor, energy
blue flame
incomplete combustion
happens when there isn’t enough oxygen
creates solid carbon, carbon monoxide, carbon dioxide, water vapor, energy
yellow flame
combustion reaction for life processes
cellular resiperation
happens in mitochondria
happens much slower than in industrial settings
C6H12O6 + O = CO2 + H2O + ATP energy + heat energy