Addition Reactions
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20 Terms
Hydrohalogenation of Alkene Transformation
Alkene to alkyl halide
Hydrohalogenation of Alkene (non ROOR) Regiochemistry and Stereochemistry
R: Markovnikov
S: Racemic
Hydrohalogenation of Alkene (ROOR) Regiochemistry and Stereochemistry
R: Anti-Markovnikov
S: Racemic
Hydrohalogenation of Alkene Reactants
Alkene + HBr in CCl4 or H2O2
Acid-Catalyzed Hydration of Alkene Transformation
Alkene to alcohol
Acid-Catalyzed Hydration of Alkene Regiochemistry and Stereochemistry
R: Markovnikov (possible rearrangement)
S: Racemic
Acid-Catalyzed Hydration of Alkene Reactants
Alkene + acid + H2O or ROH
Oxymercuration-Demercuration of Alkene Transformation
Alkene to alcohol
Oxymercuration-Demercuration of Alkene Regiochemistry and Stereochemistry
R: Markovnikov
S: Racemic
Oxymercuration-Demercuration of Alkene Reactants
Step 1: Alkene + Hg(OAc)2 + nucleophile, H2O, or ROH
Step 2: Mercurinium ion + NaBH4
Hydroboration-Oxidation of Alkene Transformation
Alkene to alcohol
Hydroboration-Oxidation of Alkene Regiochemistry and Stereochemistry
R: Anti-Markovnikov
S: Syn addition
Hydroboration-Oxidation of Alkene Reactants
Step 1: Alkene + BH3 in THF
Step 2: H2O2 + NaOH
Catalytic Hydrogenation of Alkene Transformation
Catalytic Hydrogenation of Alkene Regiochemistry and Stereochemistry
R: Both sides add H
S: Racemic syn addition
Catalytic Hydrogenation of Alkene Reactants
Alkene + H2 + metal (Pt or Pd)
Halogenation of Alkene Transformation
Alkene to alkyl dihalide
Halogenation of Alkene Regiochemistry and Stereochemistry
R: Vinyl
S: Syn for trans, anti for cis
Halogenation of Alkene Reactants
Note 
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