alkanols, ethers and amines

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24 Terms

1
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what are alkanols

alcohols made from alkanes

2
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describe the naming system of alcohols

(what conformation the double bond is) - what alkyl group and what positon its at-how many carbons there ar in the chain - ol

3
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why are alcohols polar molecues

the electronegitive hydroxyl group pulls C-OH away

4
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what happens to them when mixed with water

hydrohen bonds form between the OH and H2O

5
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what happens at they increace in size

water solubility decreaces and boilimg point increaces

6
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what are the 3 structures that alcohols can have and what is this dependant on

primary, secondary and tertiary dependant on where the oh group is bonded

7
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whatis the primery alcohol layout

oh group bonded at the end

8
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what is the secondary alcohol layout

the oh is bonded in the middle

9
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what is the teritary alcohol layout

oh is bonded in the midlle to a carbon that bonded to another r gorup

10
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describe the substitution reaction of alcohols

they react with compounds containing halide ions - the hydroxyl group is replaces with the haylide froming haloalkane - also requires the addition od an acid

11
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describe the dehydration reaction of alcohols

the removal of water with acid catylist forming alkene - forming a new double or triple pi bond

12
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what are the 2 possible products form an elimination reaction what does this repend on

which side of the hydroxyl the hydrogen is eliminated from

13
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what is saytzeffs rule

the dehydration of an alcohol results in a higher substituted alkane

14
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what are primary alcohols oxidised to

aldyhydes then carboxylic acids

15
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what are secondary alcohols oxidised to

ketones only

16
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what are tertiary alcohols oxidised to

they wont be oxidised

17
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what is the naming culture for ethers

select the longest chain as alkane the shortest one then becones alk-oxy group subsident

18
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compare the polarity of ethers

more polar than alkanes but significently less then alcohols

19
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what are ether commonly used as, why

solvents due to little chemical activity

20
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what are amines

organic derrivitives of ammonia

21
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whats the name culture for amines

similar to alcohols

22
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what does the bonding of amine groups and hydrogen result in

the formation of ammonium salts

23
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describe amines as bases

thers a lone pair of electrons on the nitrogen that able to accept protons

24
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what is the amine chemistry demoninated by

the versitility of the nitrogen lone pair