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HBr
adds Br to alkenes, Mark.
HCl
adds Cl to alkenes, Mark.
Cl2
Br2
NBS
allylic bromination, forms 2 products
PBr3
converts alcohols to alkyl bodies (1 OHs)
inversion of configuration
SOCl2
converts alcohols to alkyl bodies (2 OHs)
mostly inversion
grigard reagent
R-Mg-X
formed by adding Mg + ether to hydrocarbon
gilman reagent
(CH3)2CuLi
gilman reactions
R2CuLi —> adds R
side products are CH3Cu and LiI
radical halogenation
hydrogen on alkene is replaced by a halogen
initiation
propagation
termination
preparing alkyl halides
anti addition, mark. product