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what are fats/lipids soluble in
organic solvent
what are the 3 classes of lipids
simple, compound, sterols
do plants & animals synthesize even or odd-numbered FA
even
how would a ruminant animal be able to acquire odd-numbered FA
through the bacteria present in rumen
what is stored in the body; FFA or triglycerides
triglycerides
what is an example of a simple lipid
vegetable oil and animal fat
What is an example of a compound lipid
glycolipids, lipoprotein, phospholipids
what is an example of a sterol
cholesterol, estrogen, testosterone
what do FA do for lipid nutrition
structure, composition, metabolizability
what makes up a triglyceride
one glycerol, three fatty acids, connected by ester bonds
what is the name of the reaction that combines glycerol and fatty acids to form a triglyceride
esterification
what is the primary form of lipid storage in animals
fat
what is the primary form of lipid storage in plants
oil
when is fat stored
excess of energy in diet
when is fat broken down
negative energy balance
classes of fatty acids
saturated and unsaturated
difference between saturated and unsaturated fatty acids
saturated has no double bonds, unsaturated has one or more
are saturated fatty acids primarily solid or liquid
solid ex. butter
difference between cis and trans fatty acids
cis has the H atom present in the same plane, trans are on two different planes
will cis bonds be liquid or solid at room temp, why, example
liquid, there is a kink that stops the FA from packing tightly, ex. vegetable oil
what is the difference between n-3 and n-6
the position of the first double bond
which has the lower melting point: short or long chain FA
Short
which has the higher melting point: saturated or unsaturated FA
saturated FA
examples of essential FA
linoleic, linolenic, arachidonic
why are fats important in the animals body
major source of energy
3 functions of fats in animals
energy, insulation, parts of cell memebrane
what are the two steps of lipid digestion
emulsification, enzymatic
what are the major organs in lipid digestion (monogastrics)
stomach, small intestine
which enzyme is responsible for lipid digestion in the stomach
gastric lipase
why is lipid digestion limited in the stomach
low pH
which organ is the major site of lipid digestion in a mature animal
small intestine
where are bile slats produced and stored?
produced in the liver, stored in gallbladder
what is the role of bile salts in digestion of fats/lipids
they can attract both fats and water, start of emulsification
which enzyme is responsible for the digestion of triglycerides in the small intestine
pancreatic lipases
what are the end-products of enzymatic digestion in the small intestine
2 free fatty acids, 1 monoglyceride
what is the purpose of micelle formation in the small intestine
transport products to brush border
what makes up micelles
bile salts, fatty acids, monoglycerides, vitamins and chloesterol
what products of fat digestion are absorbed by simple diffusion
FA, monoglycerides, glycerol, cholesterol, fat soluble vitamins
what happens to the bile salt once the fat compounds enter the enterocytes
recycled to help with emulsification of fat and forming micelles
what happens to the short chain FA in the enterocyte
directly absorbed into bloodstream
what happens to the long chain FA in the enterocyte
need help to be absorbed and transported to the bloodstream
what happens to the long chain FA & monoglycerides
made into triglycerides
what happens to the cholesterol & fat soluble vitamins
put into chylomicrons
what is the purpose of chylomicrons
transport vehicles for lipids to the lymphatic system to the bloodstream
which circulatory system do chylomicrons enter first
lymphatic system
what happens with the profile of FA in swine carcasses when we feed pigs with a finishing diet rich in sources of unsaturated FA
the carcass will be rich in unsaturated FA, be soft and excrete liquid, more prone to oxidation and soft bellies
major difference in chylomicron absorption between pigs and chickens
absorbed into bloodstream then to liver and transported/ distributed to body
which enzymes is more active in newborn animals and why
gastric lipase, because of low pH and the body is naive
how do neonatal animals digest fats in their diet
colostrum & milk contains lipases
what are the end-products of the hydrolysis of triglycerides in the rumen
glycerol and free fatty acids
after triglycerides are hydrolyzed what happens with glycerol
fermented into propionate to glucose in the liver
what are the end-products of the hydrolysis of glycolipids in the rumen
glycerol, FFA, CHO
after glycolipids are hydrolyzed what happens with glycerol & CHO
propionate and energy
what happens with unsaturated FA in the rumen
biohydrogenation
adding of H atoms to unsaturated FA, H atoms replace double bonds, FA becomes saturated
what is biohydrogenation
why unsaturated FA need to be biohydrogenated
unsaturated FA are toxic, digestion is reduced
the majority of the FFA leaving the rumen enters the abomasum as (blank) FA
saturated
why is fat deposition in ruminants not the same as what they est
biohydrogenation
what cause milk fat depression
conjugated linoleic
what happens with saturated FA in the rumen
dont undergo biohydrogenation, pass through rumen unaltered
what types of fats/FA can be used in ruminants diets
unsaturated, saturated, rumen protected fat
what are examples of rumen protected fat
calcium soap, prilled fat
pass to the abomasum unchanged, low pH make fat available to enter SI, benefits energy density without negative effects on rumen, fermentation and doesnt have milk fat depression
benefits of using rumen protected fat
when more energy is consumed what are the fates of lipids
stored in body as fat
when the animal is in negative energy balance with are the major fates
oxidized for energy
what is lipogenesis
synthesis of FA from non-lipid sources
what are the two key enzymes for lipogensis
acetyl-CoA carboxylase, Fatty acid synthetase
what are the steps of de novo
fatty acid synthesis, elongation, desaturation, esterification
what are the major precursors for fat synthesis in ruminants
acetate and BHBA
what are the two steps of lipid degradation
lipolysis, B-oxidation
what are the end products of lipolysis
glycerol, FFA
which enzymes plays a key role in lipolysis
hormone-sensitive lipase
what is the major goal of B-oxidation
ATP production