ISU - Organic Chem Families and Characteristics

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Functional group of amines

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36 Terms

1

Functional group of amines

R-NH2

<p>R-NH2</p>
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2

Functional group of amides

O=C-N-R-R

<p>O=C-N-R-R</p>
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3

Functional group of aldehydes

R-C=O

<p>R-C=O</p>
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4

Functional group of ketones

C-C=O-C

<p>C-C=O-C</p>
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5

Functional group of carboxylic acids

R-C=O-OH

<p>R-C=O-OH</p>
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6

Functional group of Esters

R-C=O-O-R

<p>R-C=O-O-R</p>
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7

Functional group of alcohols

O-H

<p>O-H</p>
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8

Functional group of ethers

R-O-R

<p>R-O-R</p>
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9

Functional group of thiols

R-S-R

<p>R-S-R</p>
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10

What is the suffix for amines?

amine

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11

What is the suffix for amides?

amide

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12

What is the suffix for aldehudes?

al

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13

What is the suffix for ketones?

one

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14

What is the suffix for carboxylic acids?

oic acid

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15

What is the suffix for esters?

yl, oate

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16

What is the suffix for alcohols?

ol

diol

triol

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17

What is the suffix for ethers?

ether

longer sub oxy

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18

What is the suffix for thiols?

thiol

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19

How do you simply name amines?

substituents + root-amine

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20

How do you simply name amides?

substituents + acid root-amide

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21

How do you simply name aldehydes?

subs - parent - locate C=O

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22

How do you simply name ketones?

subs - parent - locate C=O

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23

How do you simply name carboxylic acids?

location of functional takes precedence in numbering over other bonds

number where functional is located

subs - parent/bonds in chain - oic acid

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24

How do you simply name esters?

find alcohol

alcohol - yl - carboxylic acid - oate

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25

How do you simply name alcohols?

subs- parent-locate and number of functional - suffix

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26

How do you simply name ethers?

subs, parent, root ether orshorter sub oxy, then ether

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27

How do you simply name thiols?

subs- parent-thiol

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28

How do intermolecular forces affect amines polarity, solubility?

  • Primary amines are more polar than others

  • Hydrogen bonding creates the polarity

  • As solubility decreases, chain length increases

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29

How do intermolecular forces affect amides polarity?

  • Primary and secondary amides are more polar than tertiary

  • Hydrogen bonding creates the polarity

  • Tertiary cannot create H bonds

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30

How do intermolecular forces affect aldehydes polarity?

  • H bonding increases boiling point

  • Slightly less polar than ketones

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31

How do intermolecular forces affect ketones polarity?

  • H bonding increases boiling point

  • Slightly more polar than aldehydes

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32

How do intermolecular forces affect carboxylic acid polarity?

  • Polar due to O atom

  • Soluable

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33

How do intermolecular forces affect esters polarity?

  • Polar

  • Lower bp that carboxylic acids2

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34

How do intermolecular forces affect alcohols polarity?

  • Polar

  • Soluable

  • high bp

  • e- OH

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35

How do intermolecular forces affect ethers polarity?

  • weak polarity due to C-O

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36

How do intermolecular forces affect thiols polarity?

  • less polar than alcohols

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