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Maybe I'll add why the work is significant later
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Jan van der Straet (Flemish), Invention of Oil Painting (c. 1600), Engraving

Giorgio Vasari (Italian), The Lives of the Most Eminent Painters, Sculptors and Architects (1550)

Masaccio (Tommaso di Ser Giovanni di Simone) (Italian), Trinity with the Virgin, St. John the Evangelist, and Donors. (c. 1425), Fresco

Michelangelo Buonarroti (Italian), David (c. 1500), marble

Raphael (Raffaello Sanzio) (Italian), Madonna in the Meadow, (c. 1505). Oil on wood

Quentin Massys (Dutch), The Money Changer and His Wife, 1514. Oil on panel

Dirck van Delen (Dutch), Iconoclasm in a Church, 1630, oil on panel

Angelica Kauffman (Swiss-English), Self-Portrait Hesitating Between Painting and Music (c. 1795), oil on canvas

Anna Ruysch (Dutch), A still life of flowers, c.1690s, oil on canvas

Hyacinthe Rigaud (French), Louis XIV (1701), oil on canvas

Jean-Antoine Houdon (French), George Washington, c. 1790, marble

Antoine Watteau (French), Return from Cythera, c. 1717, oil on canvas

Jacques-Louis David (French), Oath of the Horatii (c .1785) Oil on canvas

Justus Kuehn (colonial American), Unnamed attendant and Henry Darnall III (1720), oil on canvas

Thomas Cole (American), The Oxbow, c. 1830. Oil on canvas

George Catlin (American), The Light Going To and Returning From Washington, (c. 1840), oil on canvas

Eastman Johnson (American), A Ride for Liberty, The Fugitive Slave (c. 1865), oil on canvas

Henry Mosler (American), The Lost Cause (c. 1870), oil on canvas

Gustave Courbet (French), The Stone Breakers, (1849). Oil on canvas

Joseph Nicéphore Niépce (French) , View from the Window at Le Gras (c. 1826), heliograph on pewter

Lewis Wickes Hine (American), Ten-Year-Old Spinner, North Carolina Cotton Mill, 1908, gelatin silver print

Thomas Eakins (American), The Gross Clinic , 1875. Oil on canvas

Jeff Wall (Canadian), Picture for Women, 1979, transparency in lightbox

Louis Sullivan (American), Guaranty Building, Buffalo, New York, c. 1895

Walter Gropius (German-American), Bauhaus, Dessau, Germany, c. 1925

Philip Johnson and others (American), Sony Building, New York, c. 1980.