Ethers and Epoxides

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9 Terms

1
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OH to Br

PBr3 inversion

2
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OH to Cl

SOCl2, pyr

3
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OH to OTs

ClTs, pyr

4
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Ether

  1. NaO

  2. RCH2Br

5
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alkyoxymerucation-demurcation

  1. Hg(OAc)2, ROH

  2. NaBH4

    anti ethers

6
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radical

Br on more substitures, Br2,hv/NBS benzylic

7
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Acidic Cleavage on ether

HX X and H2O

8
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Halohydrin to expoxide

1.X2, H2O

2.NaH

syn

9
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Epoxide ring opening

base, H2o mark acid, H2O anti-mark

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