Chem 211 - Chapter 8: Addition Reactions
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18 Terms
Is hydrohalogenation stereospecific?
No, stepwise rxn, OH added to more substituted
Is hydrohalogenation regioselective?
Yes, Mark’s product
Is halogenation stereospecific?
Yes, stepwise and anti add’n
Is halogenation regioselective?
No, Br is added twice
Is hydrogenation stereospecific?
Yes, syn-add’n
Is hydrogenation regioselective?
No, H is added twice
Is hydration by OxyHg DeHg stereospecfic?
Yes, anti add’n
Is hydration by OxyHg DeHg regioselective?
Yes, Mark’s product
Is hydroboration stereospecific?
Yes, syn add’n
Is hydroboration regioselective?
No, anti Mark’s products
Is OsO4 dihydroxylation stereospecific?
Yes, syn add’n
Is OsO4 dihydroxylation regioselective?
No, two OH groups
Is peroxide dihydroxylation stereospecific?
Yes, anti add’n
Is peroxide dihydroxylation regioselective?
No, two OH groups
Is does oxidative cleavage have special considerations?
KMNO4 is harsh and H will turn into alcohol
What will make a halogen in a hydrohalogenation rxn have an antimark’s product?
peroxide
Is an acid catalyzed hydration rxn stereospecific?
No, because stepwise C+
Is an acid catalyzed hydration rxn regiospecific?
Yes, mark’s product
Note 
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