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define a mineral
naturally occurring, inorganic, crystalline solid with a definite chemical comp.
What controls mineral classification?
dominant anion or anionic group
What allows small variations in mineral chemistry?
Solid solution between similar ions
Are all rocks made of minerals?
No, coal and obsidian aren’t
Mineral species vs. Group?
Species = distinct mineral; group = related species
How does electron loss/gain affect charge?
lose an election, gain cation; gain election, gain anion
5 main bond types?
ionic, covalent, metallic, van der waals, hydrogen
Ionic vs. covalent bond property difference?
ionic = brittle; covalent = hard & strong
Why does ionic radius vary?
coordination number and charge
which ion has CN=12 with O^-2?
K^+
What do higher P and T do to substitution?
P favors small ions; T allows more variability
Goldschmidt’s first rule?
Ionic radii must differ by 15%
Example of simple substitution?
Mg²+ and Fe²+ in olivine
What promotes nucleation?
undercooling and high supersaturation.
Why small crystals in extrusive rocks?
rapid cooling = many nuclei = small crystals
define polymorphs
Same chemistry, different crystal structure
Pseudomorph example?
limonite replacing pyrite
3 polymorphism types
displacive, reconstructive, order-disorder
What does metamict mean
radiation-damaged, amorphous mineral
5 silicate structures and Si:O ratios
Isolated 1:4, Single chain 1:3, Double 4:11, Sheet 2:5, Framework 1:2
Unit cell definition?
Smallest repeating 3D unit of a crystal lattice
6 crystal systems?
Cubic, tetragonal, orthorhombic, hexagonal, monoclinic, triclinic.
Miller indices for planes?
hkl); directions = [uvw].
Refraction vs reflection?
Refraction bends light; reflection bounces it
Isotropic vs anisotropic minerals?
Isotropic = same in all directions (cubic); anisotropic = varies (quartz).