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The three Biogeochemical cycles
The carbon cycle, nitrogen cycle, phosphorous cycle
Reservoirs of carbon and their forms
The atmosphere- C02, methane,
The hydrosphere- carbonic acid, hydrogen carbonate ions
lithosphere-carbonate rocks eg limestone
biosphere- all biological molecules eg lipids, proteins, DNA
Carbon cycle photosynthesis
Photosynthesis- plants absorbing c02 from atmosphere and h20 then convert to glucose which gets stored in their biomass. A form of carbon sequestration
Carbon cycle respiration
Respiration- aerobic (with oxygen) anaerobic (without oxygen), they both release energy from biological molecules such as carbohydrates to power an organisms metabolism. Aerobic releases more energy than anaerobic. Aerobic releases c02 into the atmosphere but aneroid releases methane
Carbon cycle water bodies
C02 dissolved into wster to form carbonic acid which breaks down into a bicarbonate ion and a hydrogen ion which increases the acidity of the ocean, this is reversible so c02 can reform and exsolve out of water bodies returning to the atmosphere
Carbon dioxide food chains/webs
Plants use sunlight to synthesis carbohydrates and store in their biomass, when eaten by herbivores the carbon is transferred and transferred again if eaten by a predator. Decomposers break down waste returning the carbon contained within back into the atmosphere
The carbon cycle processes
Photosynthesis, respiration, water bodies, food chains/webs
Define fossilisation
The formation of long term carbon stores such as fossil fuels and carbonate rocks
Human activities effecting the carbon cycle
Deforestation- reduces photosynthesis slowing rate of carbon sequestration from atmosphere into biomass, wood harvested can then be burned to release the c02 into the atmosphere
Shipping- release oil and heavy metals into the ocean polluting water and killing photosynthesising organisms reduces volume of carbon dioxide they can take up
Agriculture- soil can be aerated ploughing and installing drainage systems to prevent flooding encouraging aerobic respiration
Creating anaerobic sites such and landfill
Fixing human created problems (carbon)
Place carbon sinks/stores under protected designated areas eg SSSIs or NNRs banning any damaging activities, reducing reliance on fossil fuels like using HEP/solar/wind power
Recycling, utilising principles of the circular economy to reduce the volume of waste sent to landfills reducing the the volume of methane released
Define Biogeochemical cycles
Processes allowing the cycle of essential nutrients through biotic and abiotic components of the earth
Aerobic respiration
Respiration with oxygen releasing more energy snd carbon dioxide
Anaerobic respiration
Respiration without oxygen releasing less energy and methane
Carbonic acid
Formed when c02 dissolved into water contributing to ocean acidity
Food chains/webs
Transfer of carbon through the consumption and decomposition of organisms in ecosystems
Combustion
The process of burning a fuel source to release energy
Carbon sinks/stores
Natural/artificial reservoirs that accumulate and store carbon compounds
Which reservoir does Carbon Capture storage happen in
The lithosphere
Which reservoir does carbon sequestration happen in
The biosphere
Nitrogen reservoirs and forms
Atmosphere- nitrogen gas, nitrous oxide gases
Hydrosphere- dissolved nitrates, ammonium ions
Lithosphere- nitrates, nitrites, ammonium compounds in the soil
Biosphere- genetic material eg DNA and proteins
Roles of microorganisms in the nitrogen cycle
Decomposition- breakdown of DOM to release ammonia/ ammonium ions into the soil
Nitrogen fixation- converting nitrogen gas into a more usable form by breaking the triple bond and releasing the 2 nitrogen atoms
Nitrification- where they convert ammonium ions into nitro gates and then nitrates in a series of oxidation reactions in the soil Nitrogen fixation
Denitrification- converting nitrates in the soil to nitrates in the soil to nitrogen gas which gets released into the atmosphere
Nitrogen fixation
When nitrogen gas is converted into any other usable for eg nitrates/ammonium. Cannot be used by living organisms as they don’t have the enzyme to break the triple bond but there are bacterial species that do known as nitrogen fixers as they convert it into a form that organisms can use to make DNA and proteins
Nitrogen fixation processes -Haber process
Artificial process used to make the inorganic fertilisers in agriculture. Nitrogen and hydrogen are brought together in high temps and pressures by combustion of fossil fuels to form ammonia -not sustainable but can increase soil fertility
Name the nitrogen fixation processes
Haber process, ionisation, fixation by soil bacteria, fixation in legumes
Nitrogen fixation processes - fixation in legumes
Pea/bean plants that form a symbiotic relationship with nitrogen fixation bacteria species that live in root nodules. The bacteria have the enzyme nitrogenase which hydrolyses the triple bond in nitrogen gas and give the products to the plant. In return the plant provides bacteria with sugars made in photosynthesis eg sucrose
Nitrogen fixation processes -Ionisation
When lightning causes oxygen and nitrogen in the atmosphere to fuse and create oxides of nitrogen which happens due to the high energy of the lighting which makes the reaction take place
Ammonification
The formation of ammonium ions carried out by bacteria in the soil using DOM eg leaf litter. This processes is essential in increasing soil fertility as nitrates are the easiest form of nitrogen for plants to absorb through their roots, the bacteria are aerobic so require oxygen in order to complete the process so aerated and well drained soils are needed
Simple 3 steps: ammonium ions are oxidised into nitrites and those are oxidised into nitrates
Nitrogen fixation processes -fixation by bacteria
Free living bacterial species naturally found in soil that have the enzyme to break the triple bond in nitrogen gas so they can utilise the nitrogen to build their DNA and proteins
Nitrification
A process that used ammonium ions carried out by nitrifying bacteria in the soil that converts the ammonium ions into nitrites in a series of oxidation reactions
Denitrification
Denitrifying bacteria convert nitrates in the soil to nitrogen and nitrous oxide gases in the atmosphere, happens in anaerobic soils reducing soil fertility especially if soils are compacted or waterlogged
Name that human impacts on the nitrogen cycle
Ploughing and installing water drainage systems, Inorganic fertilisers, fossil fuels
Human impacts on nitrogen cycle -fossil fuels
Combustion of fossil fuels in vehicle engines involves high temps in the engine causing nitrogen and oxygen to bond and create nitrous oxide gases which are released into the exhaust gases
Human impacts on nitrogen cycle -ploughing and wster drainage
increase the aeration of the soil encouraging nitrification. But using heavy machinery/livestock will compact soil increasing flood risk and rates of denitrification
Human impacts nitrogen cycle -inorganic fertilisers
release large volumes of nitrates into the soil at once which plants can’t absorb all at once which then increases nitrous oxide gases in the atmosphere. Increase of nutrients in the water can cause algal blooms on the surface blocking sunlight from reaching submerged plants which then die and take oxygen out of the water by increasing number of aerobic decomposing bacteria -eutrophication
Methods to increase the sustainability of the nitrogen cycle
Reducing reliance of fossil fuels, manage agricultural practices
Methods to increase the sustainability of the nitrogen cycle -reduce fossil fuels
Helps reduce the volume of nitrogen oxide gases into the atmosphere, instead use electric or hydrogen powered cars and switching to renewable energy sources for electricity generation as well as utilising clean up techniques to prevent nitrous oxide release from cars/exhaust gases such as a catalytic converter
Methods to increase the sustainability of the nitrogen cycle -agricultural practices
To recuse reliance on inorganic fertilisers to increase soil fertility eg using organic fertilisers such as manure which decompose to release nitrogen more slowly reducing chance of leaching.
Cultivating leguminous crops as they don’t require inorganic fertilisers to gain nitrogen.
Minimal use of pesticides so that soil biota aren’t harmed
Bond found in nitrogen gas
Triple covalent bond
What is an enzyme
Biological catalyst that speeds up the rate of reaction
How does the phosphorous cycle differ to the other cycles
It does not have a gaseous form so will not be found in the atmosphere reservoir
The phosphorous cycle reservoirs and forms
Hydrosphere- dissolved phosphate ions
Lithosphere- phosphates in the soil and phosphorus rich rocks
Biosphere- bones, DNA, cell membranes
Name the phosphorus cycle processes
Erosion and weathering, food chains/webs, pH
Phosphorus cycle processes -erosion and weathering
Releases phosphorous from rocks but can cause leaching into nearby water bodies due to soil erosion, it can then undergo sedimentation and form rocks on the ocean bottom. If it was dissolved in the soil it could be absorbed by plant roots and then used to make biological molecules. Although plant roots are ineffective at absorbing phosphorous so could end up leaching from the soil back into water bodies.
Phosphorus cycle processes -food webs
Once plants have taken up phosphorus they can get eaten and it will transferred to the consumer. Once that organism produces waste or die then it will be decomposed by soil biota eg bacteria/fungi which releases it back into the soil and it can then be re-absorbed by other plants
Phosphorus cycle processes -pH
Soil pH can impact the solubility of phosphate ions and therefore the ease at which plants can absorb them, increased acidity increase the solubility which can lead to an increased risk of leaching and running off into nearby water bodies. Alkaline conditions decrease solubility and the ability for root absorption
Management strategies for the phosphorous cycle
Sustainability- reduce the amount of mined deposits bc the volume is depleting quickly and instead use organic fertilisers sub as manure or add mycorrhizal fungi to the soil which forms a symbiotic relationship with crop roots
Human activities affecting processes in the phosphorous cycle -extraction
Large amounts of phosphorous are extracted by mining deposits for eg. Guano which is the accumulation of bird waste and is rich in phosphorus. It’s then used I. The manufacture of inorganic fertilisers which are then spread onto fields. This mobilises phosphorous at a faster rate than natural which increase the liklihood of eutrophication
Why is the phosphorous cycle a limiting factor
The element is in the shortest supply