Acids and Bases

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Last updated 6:18 PM on 3/13/25
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7 Terms

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Organic **Basic** groups
Has lone pairs (RO- ; RNH2)

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\*Since a base must accept an H+ , **BASES** in organic chemistry have **lone pairs** to accept the H+
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Organic **Acidic** Group
Has H attached to O/electronegative atom (ROH ; R-CO2-H)

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\*Since an %%**acid must have an H+ available to donate**%%, acidic molecules in organic chemistry usually %%**have an H attached to an electronegative atom**%%
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Acid strength (type of bond)
triple bond > double bond > single bond
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Acid strength (polarity)
nonpolar doesn’t equal bad acid (see pic)
nonpolar doesn’t equal bad acid (see pic)
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Acid Strength (electronegativity)
The more spread apart the electrons, the better
The more spread apart the electrons, the better
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Acid Strength (atom size)
F>Cl>Br>I (opposite from SN2 NU!!)
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Acid Strength (pKa)
the **higher pKa** the **worse** the acid