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Levels of biological organization
Biosphere, 2. Ecosystems, 3. Communities, 4. Populations, 5. Organisms, 6. Organs, 7. Tissues, 8. Cells, 9. Organelles, 10. Molecules, 11. Atoms
Matter
anything that takes up space and has mass
Elements
a substance that cannot be broken down into other substances by chemical reactions (92 naturally occurring elements)
Compound
a substance made up of two or elements combined in fixed proportions
A compound has characteristics
different of the elements that compose it
Essential elements
elements an organism needs to survive; 20-25% of the 92 natural elements are essential (humans need 25, plants need 17)
Oxygen, Hydrogen, Carbon, and Nitrogen make up
~96% of living matter; other 4%: Calcium, Phosphorus, Potassium, Sulfur, trace elements
Trace elements
required by an organism in minute amounts
Atom
smallest unit of matter that still retains the properties of an element
Subatomic particles
neutrons, protons, electrons
Atomic nucleus
dense core at the center of an atom where protons and neutrons are packed
Dalton
unit of measurement for subatomic particles; same as the atomic mass unit (amu); neutrons + protons have masses close to 1 dalton
Atomic number
number of protons in an atom
Mass number
total number of protons and neutrons in an atom
Atomic mass
total mass of an atom
Isotopes
different atomic forms of the same atom (different number of neutrons)
Radioactive isotopes
an isotope in which the nucleus decays spontaneously giving off particles and energy; used as diagnostic tools in medicine and in advanced imaging instruments
Half-life
the time it takes for 50% of the parent isotope to decay
Radioactive dating
a process where scientists measure the ratio of different isotopes and calculate how many half-lives have passed since an organism was fossilized or a rock was formed
Energy
the capacity to cause change
Potential energy
the energy that matter possesses because of its location or structure
Electrons have potential energy because of their
distance from the nucleus
Electron shells
where electrons are found (each with a characteristic distance and energy level)
Valence electrons
determine the chemical behavior of an atom
Valence shell
outermost electron shell
Orbital
3D space where an electron is found 90% of the time; each orbital has a max of two electrons; s,p, etc.
Chemical bonds
attractions between two atoms resulting from the sharing of outer-shell electrons or the presence of opposite charges on the atoms
Bonds ranked in order of strength
Covalent, 2. Ionic, 3. H-bonds, 4. Van Der Waals
Covalent bond
sharing of a pair of valence electrons by two atoms
Molecule
two or more atoms held together by covalent bonds
Valence
the bonding capacity of an atoms; usually the number of unpaired electrons
Electronegativity
the attraction of a particular atom for the elections of a covalent bond
Nonpolar covalent bond
electrons are shared equally
Polar covalent bond
electrons are shared unequally
Ion
an atom or molecule that has gained or lost one or more electrons, gaining a charge
Cation
positive charge
Anion
negative charge
Ionic bond
a chemical bond resulting from the attraction of oppositely charged ions
Ionic compound
a compound resulting from the formation of an ionic bond (salt)
Ionic compound are not
molecules
Not all salts have the same number of
anions and cations
Hydrogen bond
the attraction between a hydrogen and an electronegative atom
Van Der Waals interactions
weak interactions between molecules/ parts of molecules that result from transient partial charges
Chemical reactions
the making and breaking of chemical bonds, leading to changes in the composition of matter
Reactant
starting material in a chemical reaction
Product
material resulting from a chemical reaction
Chemical equilibrium
in a chemical reaction, the state in which the rate of the forward reaction equals the rate of the reverse reaction, so that the relative concentrations of the reactants and products do not change with time; dynamic equilibrium
Polar molecule
a molecule with an uneven distribution of charges in different regions of the molecule
Cohesion
the linking together of like molecules, often with H-bonds; helps contribute to the transport of water and dissolved nutrients against gravity in plants
Adhesion
the clinging of one substance to another; helps counter to downward pull of gravity
Surface tension
a measure of how difficult it is to stretch or break the surface of a liquid; water has a high surface tension because of the H-bonding of surface molecules
Kinetic energy
the energy of motion
Thermal energy
kinetic energy due to the random motion of atoms and molecules
Temperature
a measure of the average kinetic energy of the atoms and molecules in a body of matter
Heat
thermal energy in transfer from one body of matter to another
Calorie
the amount of heat energy needed to raise the temperature of 1g of water by 1ºC
Kilocalorie
1000 calories
Joule
one unit of energy
Specific heat
the amount of heat that must be absorbed or lost for 1g of a substance to change temperature by 1ºC
Heat of vaporization
the amount of heat a liquid must absorb for 1g of it to be converted from a liquid to a gaseous state
Evaporative cooling
the process in which the surface of an object becomes cooler during evaporation, a result of the molecules with the greatest kinetic energy changing from the liquid to the gaseous state
Solution
a liquid that is a completely homogeneous mixture of 2+ substances
Solvent
dissolving substance
Solute
dissolved substance
Aqueous solution
the solute is dissolved in water, the solvent
Hydration shell
the sphere of water molecules around each dissolved ion
Hydrophobic
substance that appears to repel water
Hydrophilic
substance that appears to have an affinity for water
Molecular mass
the sum of the masses of all the atoms in a molecule
Mole (mol)
the number of grams of a substance that equals its molecular/ atomic mass in daltons
Avogadro's number
6.02 x 10^23
Molarity
the number of moles of solute per liter of solution
Hydrogen ion
a singular proton with a +1 charge
Hydroxide ion
water molecule that just lost a proton (OH-)
Hydronium ion
a water molecule that has an extra proton bound to it (H3O+)
Acid
substance that increases the H+ ion concentration of a solution
Base
substance that reduces the H+ ion concentration of a solution
Acid base formula
([H+][OH-]=10^-14)
pH formula
pH = -log[H+]
Buffer
a substance that minimizes changes in the concentrations of H+ and OH- in a solution by accepting H+ from the solution when they are in excess and donating H+ when they are depleted
Ocean acidification
CO2 dissolving in seawater and reacting with water to form carbonic acid, lowering the ocean’s pH; CO2 + H2O → H2CO3, H2CO3 → H+ + HCO3-, H+ + CO3(2-) → HCO3-, CO3(2-) + Ca(2+) → CaCO3
Organic chemistry
the study of carbon compounds
Miller’s experiment
proved complex organic molecules could arise spontaneously under conditions thought at the time to have existed on early Earth; used CH4, CO2, H2S, and NH3
Carbon electron shells/shape
2 in first cell, 4 in second shell; carbon forms tetrahedrons (< between bonds is 109.5º)
Carbon branches can be
straight, branched, arranged in closed rings
Hydrocarbons
an organic molecule consisting only of carbon and hydrogen
Isomers
compounds that have the same number of atoms of the same elements but different structures and hence different properties
Structural isomers
one of two or more compounds that have the same molecular formula but differ in the covalent arrangements of their atoms
Cis-trans isomers
one of several compounds that have the same molecular formula and covalent bonds between atoms but differ in the spatial arrangement of their atoms owning to the inflexibility of double bonds
Enantiomers
isomers that are mirror images of each other and that differ in shape due to the presence of an asymmetric carbon, one that is attached to four different atoms or groups of atoms
Cells are about _____% water
70-95%
Ionic compounds are not
molecules
Every water molecule can make ____ H-bonds
4
When the temperature rises H-bonds
break
When the temperature lowers H-bonds
form
Heat is _____ when H-bonds break
absorbed
Heat is _____ when H-bonds form
released
In liquid water has a maximum of ___ H-bonds
3
Acid rain has which acids?
nitric acid and sulfuric acid
pH 1
battery acid