Ochem 1 - Synthetic Transformations

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5 Terms

1
New cards

  1. Hg(OAc)2, H2O, THF (solvent)

  2. NaBH4

  • Markov addition of H and OH

  • oxymercurtion-demurcuration

<ul><li><p>Markov addition of H and OH</p></li><li><p>oxymercurtion-demurcuration</p></li></ul><p></p>
2
New cards

  1. Hg(OAc)2, HOR, THF (solvent)

  2. NaBH4

  • Markov addition of H and OR

  • alkoxymercuration-demurcuration

<ul><li><p>Markov addition of H and OR</p></li><li><p>alkoxymercuration-demurcuration</p></li></ul><p></p>
3
New cards

  1. BH3, THF (solvent)

  2. H2O2, NaOH

  • Anti-markov addition of H and OH

<ul><li><p>Anti-markov addition of H and OH</p></li></ul><p></p>
4
New cards

  1. HBr + peroxides (ROOR), heat/light

  • anti-markov addition of H and Br

<ul><li><p>anti-markov addition of H and Br</p></li></ul><p></p>
5
New cards

  1. HX (cold, dark, no peroxides) → X = Cl, Br, or I

  • Markov addition of H and X

<ul><li><p>Markov addition of H and X</p></li></ul><p></p>