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energy
the ability to do work
electrical energy
related to the movement of charged particles
thermal energy
the energy of motion in ions/molecules
potential energy
energy related to position
free energy
the energy available to do work
adenosine triphosphate
the source of energy that makes cells/organisms run
phosphorylation
the attachment of a phosphate group to a molecule resulting in a great deal of work
energy coupling
the use of free energy from spontaneous reactions to drive non spontaneous reactions
endergonic reaction
results in an increase of free energy
exergonic reaction
results in a decrease of free energy
enzymes
react as catalysts in reactions
active site
location on a protein where a reaction takes place
active site inhibition
prevents substrates from entering active site
allosteric inhibition
inhibitors bind elsewhere on enzyme and alter the shape of the active sire, prevening substrate bonding
allosteric activation
activator binds elsewhere on enzyme and alters shape of active sire to encourage substrate binding
allostery
9ther molecules can cause a conformational change in an enzyme, which alters it’s activity
kinases
enzymes that catalyze phosphorylation
metabolic pathway
a series of reactions within a cell (converting molecules into other molecules or releasing energy)
metabolism
all chemical reactions occurring in a biological system at a given time
anabolic reactions
complex molecules are made from simple molecules, and energy input is required
catabolic reaction
complex molecules are broken into simple molecules, and energy is released
reduction
gain of electron/s
oxidation
loss of electron/s
glycolysis inputs
1 glucose, 2 ATP, 2 NAD+ + Pi
glycolysis outputs
2 pyruvate, 4 ATP, 2 NADH
pyruvate processing inputs
2 pyruvate, 2 NAD+, 2 coenzyme A
pyruvate processing outputs
2 acetyl coenzyme A, 2 CO2, 2 NADH
citric acid cycle inputs
2 acetyl coenzyme A, 6 NAD+, 2 FAD+, 2 GDP + Pi
citric acid cycle outputs
2 GTP, 4 CO2, 6 NADH, 2 FADH2
electron transport train inputs
NADH, FADH2, O2, H+
electron transport train outputs
NAD+, FAD, H2O, protein gradient
ATP synthesis inputs
4 H+ per ADP, ADP + Pi
ATP synthesis outputs
ATP (28 per glucose)
oxidative phosphorylation
ATP synthesized by oxidation of electron carriers in the presence of O2
fermentation
produced ATP after glycolysis if there is no O2 available
negative feedback
high concentration of a metabolic product can inhibit action of an enzyme in pathway
positive feedback
high concentration of a metabolic product can activate an enzyme in another pathway
calvin cycle
reactions that use ATP and NADPH to reduce CO2 and produce sugars
rubisco
enzyme that catalyzes the first step of the calvin cycle
somata
small openings in plant structure that CO2 and O2 diffuse in and out of
guard cells
control the opening/closing of somata in response to environmental conditions