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These flashcards cover key concepts from the General Chemistry lecture notes about kinetics, reaction rates, and equilibrium.
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carbon-11
An isotope used in biomedical imaging with a half-life of 20.39 minutes.
half-life
The time required for half of a given sample to decay.
rate law
An equation that relates the rate of a reaction to the concentrations of reactants.
reaction rate
The speed at which reactants are converted into products.
zero order reaction
A reaction whose rate is constant and independent of the concentration of reactants.
first order reaction
A reaction where the reaction rate is directly proportional to one reactant's concentration.
second order reaction
A reaction whose rate depends on the square of the concentration of one reactant or the product of the concentrations of two reactants.
activation energy
The minimum energy required to initiate a chemical reaction.
catalyst
A substance that increases the rate of a reaction without being consumed.
equilibrium constant (K)
A number that expresses the ratio of the concentrations of products to reactants at equilibrium.
Le Chatelier's principle
A principle stating that if a stress is applied to a system at equilibrium, the system adjusts in a way that counteracts the stress.
intermediate
A species formed during the reaction that is not included in the overall reaction.
homogeneous catalyst
A catalyst that is in the same phase as the reactants.
heterogeneous catalyst
A catalyst that is in a different phase than the reactants.
average reaction rate
The change in concentration of reactants or products over a specified period.
reaction quotient (Q)
A measure of the relative amounts of products and reactants present in a reaction at any given time.
dynamic equilibrium
A state of balance where the rates of the forward and reverse reactions are equal.
molecularity
The number of molecules involved in a reaction step.
rate-determining step
The slowest step in a reaction mechanism that controls the overall reaction rate.
frequency factor (A)
A constant that represents the frequency of collisions in the context of the Arrhenius equation.
pressurized equilibrium
A state of balance that occurs when gas reactants and products are contained at high pressure.