Inorg Chem Transition Groups + Summary of Group Members

Copper

Cuprum

Bronze

alloy of Cu + Sn

Brass

alloy of Cu + Zn

Monel

alloy of Cu + Ni

Wilson’s disease

Cu toxicity

penicillamine

Cu toxicity tx

Penicillamine

Wilson’s disease tx

cupric sulfate (CuSO4)

blue vitriol

CuSO4

component of Fehling’s A rgt

CuSO4

antidote for white P poisoning

emesis

MOA of blue vitriol in white P poisoning

CuSO4 + CaOH (lime)

components of Bordeaux mixture

algicide/fungicide

use of Bordeaux mixture

Silver

Argentum

sterling silver

Ag is used in jewelries as _________ + 8% copper

Ag

possess oligodynamic action

Ag nitrate

component of tollen’s test/rgt

Ag nitrate

used in Argentometry

Ag nitrate

Used in Volhard’s method

Ag nitrate

used as pencil for warts

Ag nitrate

lunar caustic

Ag nitrate

Howe’s solution

Ag nitrate

Howe’s solution use

Ag nitrate

was used for ophthalmic neonatorum

Erythromycin

new agent for ophthalmic neonatorum

antiseptics

Silver proteinates use

argyrol

Silver proteinates: mild

protargol

Silver proteinates: strong

collargol

Silver proteinates: colloidal

gold

Aurum

unreactive bc it is very stable

gold is (reactive/unreactive)

a. Aqua regia

b. Selenic acid

Gold can only be dissolved by (2)

3:1 HCl and HNO3

composition of aqua regia

for Rheumatic arthritis

therapeutic use of gold drug prep

Auranofin

PO gold drug prep

aurothioglucose, aurothiomalate

IM gold drug prep

PO, IM

ROA of gold drug prep

Coinage metals

1B transition metals other name

Cu, Ag, Au

members of coinage metals

Volatile metals

2B Transition metals other name

Zn, Ca, Hg

members of volatile metals

Zn

2nd most abundant trace metal

Zn

found in insulin

Rinmann’s green

Zn + Na cobaltinitrite

metal fume fever

toxicity caused by zinc inhalation

parakeratosis

Zn deficiency

Zinc oxide

aka zinc white

Zinc oxide

Philosopher’s wool

sunblock

Zinc oxide use

Zinc oxide

Lassar’s paste component

topical protectant

Lassar’s paste use

ZnO + ferric oxide

Calamine component

calamine

ZnO + ferric oxide

zinc sulfate (ZnSO4)

white vitriol

ZnSO4

added to sulfurated potash in white lotion

astringent, protectant

white lotion use

Ni, Cd (NiCad)

transition metals component of batteries

Pb, Li, Ni, Cd (PbiLi Ni Cad)

metals used as component of batteries

itai itai

Cd toxicity

Cd

metal toxicity manifested by bone damage w/ renal insufficiency

Cd sulfide

WAS used as antiseborrheic

Cd sulfide

yellow sulfide

Mercury

Hydrogyrum

Hg

only liquid metal

Hg

aka quicksilver

Hg

aka asoge

cinnabar (HgS)

Hg ore

HgS

cinnabar composition

ammalgams

Hg alloy

Minamata disease

methyl Hg toxicity

chelators like BAL and EDTA

ax for Minamata disease

ammoniated Hg

white Hg ppt

calomel

Hg2Cl2

Hg2Cl2 (calomel)

mercury component of pH meter electrodes

HgCl2

Hg compound which WAS used as disinfectant

corrosive sublimate

HgCl2

Scandium

eka-Boron

Sc, Y

members of 3B transition metals

Ti, Zr, Hf

members of 4B transition metals

Ti, Ta

used as surgical implants

titanium dioxide (TiO2)

sunscreen component and opacifying agent

Zr

used before as antiperspirant but was found to cause granuloma

Vanadium (V), Niobium (Nb), Tantalum (Ta)

members of 5B transition metals

Cr

glucose tolerance factor

risk for DM

dec Cr results in

strong OA; (chromic acid, K dichromate)

Chromates are

H2CrO4

chemical formula: chromic acid

K2Cr2O7

chemical formula: K dichromate

dichromate assay

used for ethanol assay

for phosphates

use of ammonium molybdate

alkaloidat rgt

use of phosphomolybdic acid

Sonnenschein rgt

other namae for phosphomolybdic acid (PMA)

Scheibler’s rgt

other name of phosphotungstic acid (PTA)

woolframite

tungsten ore

W

has hightest melting pt of all elements

X

used in heating elements

W

used in lightbulb filaments

Chromium (Cr), Molybdenum (Mo), Tungsten (W)

members of 6B transition metals

Manganese (Mn), Technetium (Tc), Rhenium (Re)

members of 7B transition metals

pyrolusite

Mn ore