thermodynamics

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Chemistry

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20 Terms

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System

A collection of objects that can be identified.

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Surroundings

Everything else that isn't part of the system.

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Open system

Can exchange both matter and energy with its surroundings.

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Closed system

Can exchange energy with its surroundings.

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Isolated system

Cannot exchange matter or energy with its surroundings.

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First law of thermodynamics

In any closed system, a change in energy must be caused by work or heat being gained or lost.

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Temperature

The measure of average kinetic energy of all the particles in an object.

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Heat

The energy transferred between objects at different temperatures.

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Thermal conduction

The transfer of energy through collision of particles.

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Convection

The transfer of energy through the movement of a fluid.

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Radiation

Energy transferred as electromagnetic waves.

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Change of state of matter

Caused by a transfer of energy.

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Melting

Change from solid to liquid due to particles breaking away from rigid positions.

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Evaporation

Change from liquid to gas due to temperature and pressure.

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Condensation

Change from gas to liquid when gas touches a cold surface.

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Freezing

Change from liquid to solid, releasing energy.

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Heat transfer between objects

Flows from higher temperature to lower temperature.

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Particle level

Particles are in constant motion.

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Direction of heat transfer

From higher temperature to lower temperature.

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Heat transfer stop

When objects reach thermal equilibrium, with the initial temperatures adjusting to be the same.