AP Chemistry Chapter 6: Thermodynamics

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energy

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32 Terms

1

energy

the ability to do work

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2

law of conservation of energy

the law that states that energy cannot be created or destroyed but can be changed from one form to another

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3

potential energy

stored energy that results from the position or shape of an object

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4

kinetic energy

the energy an object has due to its motion

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5

heat

The energy transferred between objects that are at different temperatures

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6

work

force x distance

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7

pathway

The specific conditions that control how energy transfer is divided between work and heat

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8

state function (property)

a property that is independent of the pathway

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9

system

the chemical or physical change that you are studying

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10

surroundings

everything outside the system

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11

exothermic

Chemical Reaction in which energy is primarily given off in the form of heat

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12

endothermic

(of a chemical reaction or compound) occurring or formed with absorption of heat

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13

thermodynamics

The study of energy transformations that occur in a collection of matter.

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14

first law of thermodynamics

Energy can be transferred and transformed, but it cannot be created or destroyed.

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15

internal energy

the sum of the kinetic and potential energies of all particles in the system

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16

enthalpy

The heat content of a system at constant pressure

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17

calorimeter

an insulated device used to measure the absorption or release of heat in chemical or physical processes

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18

calorimetry

The precise measurement of heat flow out of a system for chemical and physical processes

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19

heat capacity

the number of heat units needed to raise the temperature of a body by one degree.

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20

specific heat capacity

the energy required to raise the temperature of one gram of a substance by one degree Celsius

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21

molar heat capacity

the energy required to raise the temperature of one mole of a substance by one degree Celsius

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22

constant-pressure calorimetry

the measurement of heat using a simple calorimeter to determine the changes in enthalpy (heats of reaction) for reactions occurring in solution; the pressure (atmospheric pressure) remains constant during the process

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23

constant-volume calorimetry

the measurement of heat at a constant volume to find the change in internal energy of the system; requires the use of a "bomb" calorimeter

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24

Hess's Law

the overall enthalpy change in a reaction is equal to the sum of enthalpy changes for the individual steps in the process

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25

standard enthalpy of formation

enthalpy change if 1 mole of compound in standard state were formed directly from its elements

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26

standard state

a reference state for a specific substance defined according to a set of conventional definitions

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27

fossil fuels

Coal, oil, natural gas, and other fuels that are ancient remains of plants and animals.

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28

petroleum

liquid fossil fuel; oil

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29

natural gas

flammable gas, consisting largely of methane and other hydrocarbons, occurring naturally underground (often in association with petroleum) and used as fuel.

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30

coal

A fossil fuel that forms underground from partially decomposed plant material

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31

greenhouse effect

Natural situation in which heat is retained in Earth's atmosphere by carbon dioxide, methane, water vapor, and other gases

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32

syngas

synthetic gas, a mixture of carbon monoxide and hydrogen, obtained by coal gasification

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