enthalpy definitions

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Last updated 8:43 PM on 1/29/26
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14 Terms

1
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First ionisation energy

The energy required to remove 1 electron from each atom in 1 mole of gaseous atoms to form 1 mole of gaseous 1+ ions under standard conditions: M(g) → M+(g) + e-

2
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Second Ionisation energy

the energy required to remove 1 electron from each 1+ ion in 1 mol of gaseous 1+ ions to form 1 mol of gaseous 2+ ions under standard conditions: M2+(g) → M1+(g) + e-

3
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standard enthalpy change of atomisation

the enthalpy change when one mole of gaseous atoms is formed from the element under standard conditions. NOTE - formation of 1 mole of atoms

4
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Electron Afiinity

First electron affinity: enthalpy change when 1 electron is added to each atom in 1 mole of gaseous atoms under standard conditions, to form 1 mole gaseous 1- ions

5
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Lattice Enthalpy

the energy released when 1 mole of ionic compound is formed from its constituent gaseous ions under standard conditions (298K, 100KPa) : Na+(g) + Cl- (g) → NaCl(s)

6
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Standard enthalpy change of formation

The energy released when 1 mole of ionic compound is formed from its elements under standard conditions (298K, 100kPa) with all reactants and products in their standard states. for NaCl : Na(s) + ½ Cl2(g) → NaCl(s)

7
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is second ionisation energy endothermic or exothermic?

endothermic

8
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is standard enthalpy change of atomisation endo or exo

always endothermic

9
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first electron affinity, endo or exo?

EXO

10
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second electron affinity endo or exo

endothermic

11
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enthalpy change of solution definition

the enthalpy change when 1 mol of solute is dissolved in water under standard conditions

12
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enthalpy change of hydration definition

the enthalpy change when 1 mole of gaseous ions are completely surrounded by water molecules under standard conditions

13
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is enthalpy change of hydration exo or endo

exothermic

14
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is enthalpy change of solution exo or endo

may be exothermic or endothermic

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