Unit 3: Properties of Materials and Reactions

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47 Terms

1

fluid

any substance that flows

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2

when the change of state or phase change occurs…

intermolecular attractions (forces) are either breaking or forming

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3

The strength of the intermolecular forces of the substance determines…

the amount of energy needed for the phase change

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If a substance has very strong intermolecular forces

then more energy is needed to change state/phase and a higher temperature is needed for the change as well

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5

with stronger intermolecular forces

higher melting points and higher boiling points are observed

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6

heating and cooling curves

show the temperature changes as heat (energy) is added or removed over time.

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7

the slopped parts of the graph occur when

a substance is only changing temperature and not changing state. Ex. solids getting warmer and gaining kinetic energy, speeding up, and spreading out

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8

ionic compounds don’t

sublime

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the pressure formed from the evaporating gas/vapor. (the pressure of gas above the liquid when liquid is sealed in a closed container)

vapor pressure

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the lower the boiling point…

the easier it is to evaporate and the higher the vapor pressure.

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11

at 1 atm

carbon dioxide sublimes and water does not

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12

the stronger the attraction

the greater the energy needed to make/break the attraction

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the stronger the intermolecular forces

the higher the melting point, the higher the boiling point, and the lower the vapor pressure (harder to evaporate)

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14

Intermolecular forces, strongest to weakest

ion-dipole, hydrogen bonding, dipole-dipole, ion-induced dipole, dipole-induced dipole, induced dipole-induced dipole

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an ion-dipole interaction is formed when

a cation or anion is attracted to the partial positive or partial negative of a polar molecule. these often form as a result of an ionic compound dissociating/dissolving in water

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16

a dipole-induced dipole interaction is formed when

the partial positive or partial negative of a polar molecule causes the electron cloud of a nonpolar molecule to distort and creates a temporary induced dipole in the nonpolar molecule

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an ion-induced dipole if formed when

a cation or anion causes the electron cloud of nonpolar molecule to distort and creates a temporary induced dipole in the nonpolar molecule

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the mass of the atoms or molecules impacts the strength of the induced dipoles. the more electrons an atom or molecule the more those electrons…

can move in the cloud and generate less temporary/stronger induced dipoles and stronger interactions

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19

solubility

how much of a given substance dissolves in another substance at a given temperature and can also be described as MIXING

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20

The rule for dissolving

LIKE dissolves LIKE

CHARGES dissolves CHARGES

POLAR dissolves POLAR / NONPOLAR dissolves NONPOLAR

IMF dissolves IMF

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21

the tension on the surface of the water drop is known as

surface tension

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a surfactant

a substance that reduces surface tension and increases wetting

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any dissolving medium is called the

solvent

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the dissolved particles are called the

solute

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solvation

the process of ion capture by the solvent

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aqueous solution

defined as a solution where water IS the solvent

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27

Soluble

has the ABILITY to dissolve

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Electrolytes are

metals and nonmetals - ions

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nonelectrolytes are

nonmetals and nonmetals - covalent compounds

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dissociation

the separation of ions that occurs when an ionic compound dissolves and involves aquious solutions

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Anhydrous

a substance that contains no water or water has been removed

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4 factors determine how quickly something dissolves

the identity of the solute (the identity tells you about the properties of substance like bonding, intermolecular forces, solubility, ect.

changing the temperature

agitating (stirring, shaking, mixing)

changing the surface area (breaking up chunks, crushing, grinding, spreading solute by adding slowly)

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solution

homogeneous mixtures with uniform appearance and composition - transparent and doesn’t separate

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colloid

heterogenous mixture containing particles, called the dispersed phase, that are spread throughout the substance - cloudy and doesn’t separate

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suspension

a heterogeneous mixture from which particles settle upon standing - can be separated and is also cloudy

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brownian motion

the random motion of particles due to the collisions of rapidly moving particles

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tyndall effect

the scattering of light by particles in a mixture that are of a certain size

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38

as gas solubility goes up

so does the pressure, with the opposite also being true

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39

precipitate

a solid that forms from a chemical reaction

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40

when OH- (hydroxide) is on one side of the balencing equations

use hoh

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41

when determining if it can actually happen with single replacement

use the activity series

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42

the more reactive metals in the actvity series are towards the top

and the least reactive are below that, then the halogns

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a reactive metal will replace any metals

below it

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44

the net ion equation

an equation for a reaction in solution that shows only those particles hat are directly involved in the chemical change

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45

alkali metals and what do they mean for solubility

Li, Na, K, Rb, Cs, Fr - these and the ammonium ion (NH4+) are generally soluble, as well as the acetate ion, nitrate ions and the sulfate ion

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halide ions

F-, Cl-, B-, I-

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generally insoluble ions include

carbonate ion, chromate ion, phosphate ion. sulfide ion (S-2), and the hydroxide rule

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